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pro vyhledávání: '"Connor J. Clarke"'
Publikováno v:
Nature Communications, Vol 13, Iss 1, Pp 1-6 (2022)
Pyruvic acid and its conjugate base, the pyruvate anion, are largely present in the atmosphere. Here the authors, using photoelectron imaging and quantum chemistry calculations, investigate the photochemistry of isolated pyruvate anions initiated by
Externí odkaz:
https://doaj.org/article/832db82d3a8648878b514f5fdc3d3ea3
Publikováno v:
Physical Chemistry Chemical Physics, 2021, Vol.23(34) [Peer Reviewed Journal]
Two-dimensional photoelectron spectroscopy using nanosecond and femtosecond lasers has been used to study the protopophyrin IX dianion at photon energies between 1.8-4.1 eV. The photoelectron spectra indicated the presence of two direct detachment ch
Autor:
James N. Bull, Cate S. Anstöter, Mark H. Stockett, Connor J. Clarke, Jemma A. Gibbard, Evan J. Bieske, Jan R. R. Verlet
Publikováno v:
The journal of physical chemistry letters, 2021, Vol.12(49), pp.11811-11816 [Peer Reviewed Journal]
Internal conversion between valence-localized and dipole-bound states is thought to be a ubiquitous process in polar molecular anions, yet there is limited direct evidence. Here, photodetachment action spectroscopy and time-resolved photoelectron ima
Publikováno v:
Nature communications. 13(1)
The photochemistry of pyruvic acid has attracted much scientific interest because it is believed to play critical roles in atmospheric chemistry. However, under most atmospherically relevant conditions, pyruvic acid deprotonates to form its conjugate
Publikováno v:
Clarke, C J, Gibbard, J A, Hutton, L, Verlet, J R R & Curchod, B F E 2022, ' Photochemistry of the pyruvate anion produces CO 2, CO, CH 3 –, CH 3, and a low energy electron ', Nature Communications, vol. 13, no. 1, 937 . https://doi.org/10.1038/s41467-022-28582-4
Nature communications, 2022, Vol.13(1), pp.937 [Peer Reviewed Journal]
Nature Communications
Nature communications, 2022, Vol.13(1), pp.937 [Peer Reviewed Journal]
Nature Communications
The photochemistry of pyruvic acid has attracted much scientific interest because it is believed to play critical roles in atmospheric chemistry. However, under most atmospherically relevant conditions, pyruvic acid deprotonates to form its conjugate