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Autor:
Nikita Demidov, Mateus Grebogi, Connor Bourne, Aidan P. McKay, David B. Cordes, Andreas Stasch
Publikováno v:
Molecules, Vol 28, Iss 22, p 7569 (2023)
This work reports the one-pot synthesis of sterically demanding aniline derivatives from aryllithium species utilising trimethylsilyl azide to introduce amine functionalities and conversions to new examples of a common N,N′-chelating ligand system.
Externí odkaz:
https://doaj.org/article/fb0430708ae84ca6b4b4df5b1c6589da
Publikováno v:
Angewandte Chemie. 134
We thank the University of St Andrews and the EPSRC doctoral training grant (EP/N509759/1) for support. The new ß-diketimine iPrDipnacnacH, HC(iPrCNDip)2H, Dip=2,6- iPr2-C6H3 , was converted to the magnesium(I) complex [{(iPrDipnacnac)Mg}2] and reac