Zobrazeno 1 - 10
of 10
pro vyhledávání: '"Connie J, Isaac"'
Autor:
Connie J. Isaac, Fedor M. Miloserdov, Anne-Frédérique Pécharman, John P. Lowe, Claire L. McMullin, Michael K. Whittlesey
Publikováno v:
Organometallics. 41:2716-2730
Autor:
Connie J. Isaac, Cameron I. Wilson, Arron L. Burnage, Fedor M. Miloserdov, Mary F. Mahon, Stuart A. Macgregor, Michael K. Whittlesey
Publikováno v:
Isaac, C J, Wilson, C I, Burnage, A L, Miloserdov, F, Mahon, M F, Macgregor, S A & Whittlesey, M K 2022, ' Experimental and Computational Studies of Ruthenium Complexes Bearing Z-Acceptor Aluminum-Based Phosphine Pincer Ligands ', Inorganic Chemistry, vol. 61, no. 50, pp. 20690-20698 . https://doi.org/10.1021/acs.inorgchem.2c03665
Reaction of [Ru(C 6H 4PPh 2) 2(Ph 2PC 6H 4AlMe(THF))H] with CO results in clean conversion to the Ru-Al heterobimetallic complex [Ru(AlMePhos)(CO) 3] (1), where AlMePhos is the novel P-Al(Me)-P pincer ligand (o-Ph 2PC 6H 4) 2AlMe. Under photolytic co
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::10766bb51435e560c3c5c4cbe1e06371
https://purehost.bath.ac.uk/ws/files/255636611/Whittlesey_Macgregor_revised_MS.pdf
https://purehost.bath.ac.uk/ws/files/255636611/Whittlesey_Macgregor_revised_MS.pdf
Autor:
Connie J, Isaac, Cameron I, Wilson, Arron L, Burnage, Fedor M, Miloserdov, Mary F, Mahon, Stuart A, Macgregor, Michael K, Whittlesey
Publikováno v:
Inorganic chemistry. 61(50)
Reaction of [Ru(C
Autor:
Michael K. Whittlesey, Sara Sabater, William J. M. Blackaby, Heidi Née Schneider Schmidt, Mary F. Mahon, Nasir A. Rajabi, Udo Radius, Stuart MacGregor, Maximilian W. Kuntze-Fechner, Thomas Zell, Harry Grieve, David Schmidt, John P. Lowe, Connie J. Isaac
Publikováno v:
Chemistry – A European Journal. 27:13221-13234
The addition of PPh2 H, PPhMeH, PPhH2 , P(para-Tol)H2 , PMesH2 and PH3 to the two-coordinate Ni0 N-heterocyclic carbene species [Ni(NHC)2 ] (NHC=IiPr2 , IMe4 , IEt2 Me2 ) affords a series of mononuclear, terminal phosphido nickel complexes. Structura
Autor:
Connie J, Isaac, Fedor M, Miloserdov, Anne-Frédérique, Pécharman, John P, Lowe, Claire L, McMullin, Michael K, Whittlesey
Publikováno v:
Organometallics. 41(19)
Treatment of [Ru(PPh
Autor:
Connie J. Isaac, William J. M. Blackaby, Michael K. Whittlesey, Samuel E. Neale, Stuart MacGregor, Sara Sabater
Publikováno v:
Blackaby, W J M, Neale, S E, Isaac, C J, Sabater, S, MacGregor, S A & Whittlesey, M K 2019, ' N-Heterocyclic Carbene Non-Innocence in the Catalytic Hydrophosphination of Alkynes ', ChemCatChem, vol. 11, no. 7, pp. 1893-1897 . https://doi.org/10.1002/cctc.201900220
Studies on alkyne hydrophosphination employing nickel-NHC catalysts (NHC=N-heterocyclic carbene) revealed that the free N-alkyl substituted NHCs themselves were catalytically active. DFT calculations showed the mechanism involves the NHC acting as a
Autor:
Sara, Sabater, David, Schmidt, Heidi Née Schneider, Schmidt, Maximilian W, Kuntze-Fechner, Thomas, Zell, Connie J, Isaac, Nasir A, Rajabi, Harry, Grieve, William J M, Blackaby, John P, Lowe, Stuart A, Macgregor, Mary F, Mahon, Udo, Radius, Michael K, Whittlesey
Publikováno v:
Chemistry (Weinheim an Der Bergstrasse, Germany)
The addition of PPh2H, PPhMeH, PPhH2, P(para‐Tol)H2, PMesH2 and PH3 to the two‐coordinate Ni0 N‐heterocyclic carbene species [Ni(NHC)2] (NHC=IiPr2, IMe4, IEt2Me2) affords a series of mononuclear, terminal phosphido nickel complexes. Structural
Autor:
Fedor M, Miloserdov, Connie J, Isaac, Madeleine L, Beck, Arron L, Burnage, James C B, Farmer, Stuart A, Macgregor, Mary F, Mahon, Michael K, Whittlesey
Publikováno v:
Inorganic chemistry. 59(21)
The preparation and reactivity with H
Autor:
Connie J. Isaac, James C. B. Farmer, Arron L. Burnage, Madeleine L. Beck, Michael K. Whittlesey, Stuart MacGregor, Mary F. Mahon, Fedor M. Miloserdov
Publikováno v:
Inorganic Chemistry, 59(21), 15606-15619
Miloserdov, F, Isaac, C, Beck, M, Burnage, A, Farmer, J, Macgregor, S, Mahon, M & Whittlesey, M 2020, ' Impact of the novel Z-acceptor ligand bis{(ortho-diphenylphosphino)phenyl}zinc (ZnPhos) on the formation and reactivity of low-coordinate Ru(0) centers ', Inorganic Chemistry, vol. 59, no. 21, pp. 15606-15619 . https://doi.org/10.1021/acs.inorgchem.0c01683
Inorganic Chemistry 59 (2020) 21
Miloserdov, F, Isaac, C, Beck, M, Burnage, A, Farmer, J, Macgregor, S, Mahon, M & Whittlesey, M 2020, ' Impact of the novel Z-acceptor ligand bis{(ortho-diphenylphosphino)phenyl}zinc (ZnPhos) on the formation and reactivity of low-coordinate Ru(0) centers ', Inorganic Chemistry, vol. 59, no. 21, pp. 15606-15619 . https://doi.org/10.1021/acs.inorgchem.0c01683
Inorganic Chemistry 59 (2020) 21
The preparation and reactivity with H2 of two Ru complexes of the novel ZnPhos ligand (ZnPhos = Zn(o-C6H4PPh2)2) are described. Ru(ZnPhos)(CO)3 (2) and Ru(ZnPhos)(IMe4)2 (4; IMe4 = 1,3,4,5-tetramethylimidazol-2-ylidene) are formed directly from the r
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::35e86d33625d43df1d49f306578c0847
https://research.wur.nl/en/publications/impact-of-the-novel-z-acceptor-ligand-bisortho-diphenylphosphinop
https://research.wur.nl/en/publications/impact-of-the-novel-z-acceptor-ligand-bisortho-diphenylphosphinop
Autor:
Samuel E. Neale, Guy Bertrand, Rodolphe Jazzar, Stuart MacGregor, Michael K. Whittlesey, Daniel R. Tolentino, Connie J. Isaac
Publikováno v:
Journal of the American Chemical Society
Journal of the American Chemical Society, American Chemical Society, 2019, 141 (25), pp.9823-9826. ⟨10.1021/jacs.9b04957⟩
Tolentino, D, Neale, S, Isaac, C, Macgregor, S, Whittlesey, M, Jazzar, R & Bertrand, G 2019, ' Reductive Elimination at Carbon under Steric Control ', Journal of the American Chemical Society, vol. 141, no. 25, pp. 9823-9826 . https://doi.org/10.1021/jacs.9b04957
Journal of the American Chemical Society, American Chemical Society, 2019, 141 (25), pp.9823-9826. ⟨10.1021/jacs.9b04957⟩
Tolentino, D, Neale, S, Isaac, C, Macgregor, S, Whittlesey, M, Jazzar, R & Bertrand, G 2019, ' Reductive Elimination at Carbon under Steric Control ', Journal of the American Chemical Society, vol. 141, no. 25, pp. 9823-9826 . https://doi.org/10.1021/jacs.9b04957
It has been previously demonstrated that stable singlet electrophilic carbenes can behave as metal surrogates in the activation of strong E-H bonds (E = H, B, N, Si, P), but it was believed that these activations only proceed through an irreversible