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Autor:
Colleen M. Duff-Spence, Jean Talarmin, Christopher J. Pickett, Talib I. Al-Salih, T. Adrian George, Gerald E. Bossard
Publikováno v:
Journal of the Chemical Society, Dalton Transactions. :2263
The electrochemical reduction of the 15-electron molybdenum(III) complex [MoCl3(dpepp)], dpepp = Ph2PCH2CH2P(Ph)CH2CH2PPh2, has been studied in the presence of PPh3 under argon and under molecular nitrogen. The primary reduction of the trichloride in