Practical Aspects of Thermal Dissociation and Recombination Reactions: The Reaction Systems CF3X(+M) ↔ CF3+X (+M) with X=F, Cl, Br, and I.

Autor: Cobos, Carlos Jorge¹ (AUTHOR), Tellbach, Elsa^2,3 (AUTHOR), Sölter, Lars^2,3 (AUTHOR), Troe, Jürgen^2,3 (AUTHOR) juergen.troe@mpinat.mpg.de

Publikováno v: Israel Journal of Chemistry. Aug2023, Vol. 63 Issue 7/8, p1-8. 8p.

Shock wave and modelling study of the unimolecular dissociation of Si(CH₃)₂F₂: an access to spectroscopic and kinetic properties of SiF₂

Autor: Cobos, Carlos Jorge, Sölter, Lars, Tellbach, Elsa, Troe, J.

Publikováno v: SEDICI (UNLP)
Universidad Nacional de La Plata
instacron:UNLP

The thermal dissociation of Si(CH₃)₂F₂ was studied in shock waves between 1400 and 1900 K. UV absorption-time profiles of its dissociation products SiF₂ and CH₃ were monitored. The reaction proceeds as a unimolecular process not far from th

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=dedup_wf_001::c3653759c302b7bfadea5bdad6ee1e08
http://sedici.unlp.edu.ar/handle/10915/133175

Falloff Curves of the Reaction CF₃ (+M) → CF₂ + F (+M)

Autor: Cobos, Carlos Jorge, Knight, Gary, Sölter, L., Tellbach, E., Troe, J.

Publikováno v: SEDICI (UNLP)
Universidad Nacional de La Plata
instacron:UNLP

The thermal dissociation reaction CF₃ (+Ar) → CF₂ + F (+Ar) was studied in incident and reflected shock waves by monitoring UV absorption signals of the primary dissociation product CF₂. CF₃ radicals were produced by thermal decomposition o

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=dedup_wf_001::320098512f1dbe348f4b733c5518cfb7
http://sedici.unlp.edu.ar/handle/10915/123920

Experimental and computational investigation of the substituent effects on the reduction of Fe³⁺ by 1,2-dihydroxybenzenes

Autor: Salgado, Pablo Raúl, Contreras, David, Mansilla, Héctor D., Márquez, Katherine, Vidal, Gladys, Cobos, Carlos Jorge, Mártire, Daniel Osvaldo

Publikováno v: SEDICI (UNLP)
Universidad Nacional de La Plata
instacron:UNLP

This study reports on the kinetics of the early steps that mediate the reactions of substituted 1,2-dihydroxybenzenes (1,2-DHB) with Fe³⁺. The rate constants of the three processes identified by means of the stopped-flow technique are affected by

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=dedup_wf_001::fc416ad2edd89796de150448d7f94500
http://sedici.unlp.edu.ar/handle/10915/147730

Theoretical determination of the rate constant of the CCl2 + CCl2 - C2Cl4 association reaction

Autor: Gómez, Nicolás Damián, Azcárate, María Laura, Codnia, Jorge, Cobos, Carlos Jorge

Publikováno v: CONICET Digital (CONICET)
Consejo Nacional de Investigaciones Científicas y Técnicas
instacron:CONICET
An. (Asoc. Fís. Argent., En línea) 2016;01(27):9-13
Biblioteca Digital (UBA-FCEN)
Universidad Nacional de Buenos Aires. Facultad de Ciencias Exactas y Naturales
instacron:UBA-FCEN

En un estudio previo se determinó la constante de velocidad de la reacción CCl2+CCl2 → C2Cl4 empleando la técnica de fluorescencia inducida por láser. En el presente trabajo determinamos mediante el modelo de los canales estadísticamente adiab

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=dedup_wf_001::2176ff4fea706f19ff74e00865c73061
http://anales.fisica.org.ar/journal/index.php/analesafa/article/view/2075