Zobrazeno 1 - 10
of 87
pro vyhledávání: '"Clovis Peppe"'
Publikováno v:
Revista Principia, Vol 8, Iss 0, Pp 32-36 (2013)
Tri-haletos de índio são ácidos de Lewis reconhecidos e sua química de coordenação frente a ligantes de diversas categorias é bem estabelecida. De fato, desde complexos tetracoordenados a hexacoordenados todos, foram bem caracterizados e resul
Externí odkaz:
https://doaj.org/article/53bc539a62c94594ada1525b8582dba2
Publikováno v:
Revista Principia, Vol 0, Iss 9, Pp 57-61 (2001)
A reação de InX com CH2X2 em 1,4-dioxano ou acetonitrila forma o correspondente X2InCH2X solvatado, o qual reage com E(C6H5)3 (E= P, As, Sb) para formar X3InCH2E(C6H5)3 [...].
Externí odkaz:
https://doaj.org/article/c623ff0c03da45aab0a91deb0734a243
Publikováno v:
Revista Principia, Vol 0, Iss 7, Pp 33-34 (1999)
Compostos de índio no estado de oxidação +I são raros.
Externí odkaz:
https://doaj.org/article/0681813a12bc4a3fa7caae766510a40b
Autor:
Danielle Cangussu, Felipe T. Martins, Felipe C. Wouters, Melina de Azevedo Mello, Clovis Peppe, Robert A. Burrow, Rafael Pavão das Chagas, Jaqueline Pinto Vargas
Publikováno v:
Journal of Coordination Chemistry. 71:813-827
Bromomethyl-dibromo-indium(III), Br2InCH2Br, obtained from indium monobromide and methylene dibromide, reacts with hard and soft donor ligands to afford the corresponding indium(III) organometallic complexes. In this work, we investigated the conditi
Publikováno v:
Journal of Organometallic Chemistry. 718:52-56
In this article we present the synthesis and structural characterization of the coordination compounds trans-[InCl2(OPPh3)4][PhTeCl4], trans-[InBr2(OPPh3)4][PhTeBr4], cis-[InBr2(dmso)4][PhTeBr4] and cis-[InBr2(1,10-phen)2][PhTeBr4]. These complexes c
Autor:
Railander Alves Barcellos, Jaqueline Pinto Vargas, Robert A. Burrow, Melina de Azevedo Mello, Rubia M. Siqueira da Silva, Clovis Peppe, Fabiano Molinos de Andrade
Publikováno v:
Journal of Organometallic Chemistry. 694:2228-2233
Halogenomethyl–dihalogen–indium(III) compounds X2InCH2X (X = Br, I) obtained from indium monohalides and methylene dihalides were reacted with the soft donor ligands dialkylsulfides, R2S (R = CH3, CH2Ph) to afford the corresponding dialkylsulfoni
Autor:
Lierson Borges de Castro, Clovis Peppe
Publikováno v:
Canadian Journal of Chemistry. 87:678-683
The reactivity of indium(III) benzenechalcogenolates (chalcogen = sulfur, selenium) towards organyl halides (organyl = alkyl, allyl, benzyl, acyl) was examined. A practical one-pot method to prepare organyl phenyl chalcogenides from indium metal and
Publikováno v:
Journal of Organometallic Chemistry. 694:1918-1921
Treatment of the tetraindium cluster In4[C(SiMe3)3]4 (1) with diaryl dichalcogenides Aryl-E-E-Aryl (E = S, Se and Te) afforded the corresponding RIn(E-Aryl)2 [R = C(SiMe3)3] compounds by insertion of the monomeric fragments InR into the chalcogen–c
Publikováno v:
Journal of Organometallic Chemistry. 693:3441-3445
The indium enolate generated from indium(I) bromide and α,α-dichloroacetophenone reacts with aldehydes to produce ( syn + anti )-2-chloro-3-hydroxy-propan-1-ones which can be converted to their trans -prop-2-en-1-ones derivatives upon reaction with
Publikováno v:
Synlett. 2008:1165-1170
Indium(III) benzenechalcogenolates (chalcogen = sulfur and selenium) promote the rigorous Markovnikov hydrochalcogenation of terminal alkynes. The generality and limitations of the reaction with aminoalkynes leading to allylic amines bearing vinylic