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The U(III) mixed-sandwich compound [U(eta-C5Me4H)(eta-C8H6{SiiPr3-1,4}2)(THF)] 1 may be prepared by sequential reaction of UI3 with K[C5Me4H] in THF followed by K2[C8H6{SiiPr3-1,4}2]. 1 reacts with carbon monoxide at -30 degrees C and 1 bar pressure
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=dedup_wf_001::a6a3b3b58be34829e4bd8e05a3bd2c17
https://ora.ox.ac.uk/objects/uuid:69571777-5ea5-4c2b-9a53-0656af2f9d38
https://ora.ox.ac.uk/objects/uuid:69571777-5ea5-4c2b-9a53-0656af2f9d38
The stoichiometric reaction of 1 equiv of CO with [(U(eta-C8H6{SiiPr3-1,4}2)(eta-Cp*)] affords the linear diuranium ynediolate complex [(U(eta-C8H6{SiiPr3-1,4}2)(eta-Cp*)]2(mu-eta1:eta1-C2O2) which does not react with further CO to give the deltate d
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=dedup_wf_001::40c373b6ffaea4e247583b961c6eb4ee
https://doi.org/10.1021/ja8059792
https://doi.org/10.1021/ja8059792
Autor:
Kilpatrick AF; Department of Chemistry, School of Life Sciences, University of Sussex , Brighton BN1 9QJ, U.K., Green JC; Department of Chemistry, University of Oxford , Inorganic Chemistry Laboratory, South Parks Road, Oxford OX1 3QR, U.K., Cloke FG; Department of Chemistry, School of Life Sciences, University of Sussex , Brighton BN1 9QJ, U.K.
Publikováno v:
Organometallics [Organometallics] 2015 Oct 26; Vol. 34 (20), pp. 4816-4829. Date of Electronic Publication: 2015 Jul 04.
Autor:
Kilpatrick AF; Department of Chemistry, School of Life Sciences, University of Sussex , Brighton BN1 9QJ, U.K., Green JC; Department of Chemistry, University of Oxford , Inorganic Chemistry Laboratory, South Parks Road, Oxford OX1 3QR, U.K., Cloke FG; Department of Chemistry, School of Life Sciences, University of Sussex , Brighton BN1 9QJ, U.K.
Publikováno v:
Organometallics [Organometallics] 2015 Oct 26; Vol. 34 (20), pp. 4830-4843. Date of Electronic Publication: 2015 Jul 05.
Autor:
Evans LT; Department of Chemistry, University of Sussex, Falmer, Brighton BN1 9QJ, UK. martyn.coles@vuw.ac.nz., Farnaby JH, Coles MP, Cloke FG, Hitchcock PB
Publikováno v:
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2015 May 21; Vol. 44 (19), pp. 8950-8.
Autor:
Ansell MB; Department of Chemistry, University of Sussex, Brighton BN1 9QJ (UK)., Roberts DE, Cloke FG, Navarro O, Spencer J
Publikováno v:
Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2015 May 04; Vol. 54 (19), pp. 5578-82. Date of Electronic Publication: 2015 Apr 09.
Autor:
Button ZE; Department of Chemistry, School of Life Sciences, University of Sussex, Brighton, BN1 9QJ, UK. f.g.cloke@sussex.ac.uk., Higgins JA, Suvova M, Cloke FG, Roe SM
Publikováno v:
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2015 Feb 14; Vol. 44 (6), pp. 2588-96.
Formation of cyanates in low-valent uranium chemistry: a synergistic experimental/theoretical study.
Autor:
Kefalidis CE; Université de Toulouse et CNRS, INSA, UPS, UMR 5215, LPCNO, 135 Avenue de Rangueil, F-31077 Toulouse, France. laurent.maron@irsamc.ups-tlse.fr., Frey AS, Roe SM, Cloke FG, Maron L
Publikováno v:
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2014 Aug 07; Vol. 43 (29), pp. 11202-8. Date of Electronic Publication: 2014 Apr 28.
Autor:
Kilpatrick AF; Department of Chemistry, School of Life Sciences, University of Sussex, Brighton, BN1 9QJ, UK. f.g.cloke@sussex.ac.uk., Cloke FG
Publikováno v:
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2014 Mar 14; Vol. 50 (21), pp. 2769-71.
Autor:
Kilpatrick AF; Department of Chemistry, School of Life Sciences, University of Sussex, Brighton, BN1 9QJ, UK. f.g.cloke@sussex.ac.uk., Green JC, Cloke FG, Tsoureas N
Publikováno v:
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2013 Oct 21; Vol. 49 (82), pp. 9434-6.