Zobrazeno 1 - 7
of 7
pro vyhledávání: '"Clinton R, King"'
Autor:
Brian G. Hashiguchi, Sae Hume Park, Daniel H. Ess, Michael M. Konnick, Clinton R. King, Anjaneyulu Koppaka, Roy A. Periana, Niles Jensen Gunsalus
Publikováno v:
Angewandte Chemie. 131:2263-2267
Owing to the strong nonpolar bonds involved, selective C-H functionalization of methane and ethane to esters remains a challenge for molecular homogeneous chemistry. We report that the computationally predicted main-group p-block SbV (TFA)5 complex s
Autor:
George Durrant, Michael M. Konnick, Clinton R. King, Josh I. Wheeler, Lorna Suaava, Ashley Holdaway, Roy A. Periana, Daniel H. Ess
Publikováno v:
Dalton Transactions. 48:17029-17036
SbVF5 is generally assumed to oxidize methane through a methanium-to-methyl cation mechanism. However, experimentally no H2 is observed, and the mechanism of methane oxidation has remained unsolved for several decades. To solve this problem, density
Autor:
Ashley Holdaway, Clinton R. King, Daniel H. Ess, Nick Rollins, Roy A. Periana, Michael M. Konnick
Publikováno v:
Organometallics. 37:3045-3054
High-oxidation state main-group metal complexes are potential alternatives to transition metals for electrophilic alkane C–H functionalization reactions. However, there is little known about how selection of the p-block, main-group metal and ligand
Autor:
Clinton R, King, Ashley, Holdaway, George, Durrant, Josh, Wheeler, Lorna, Suaava, Michael M, Konnick, Roy A, Periana, Daniel H, Ess
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 48(45)
Sb
Autor:
Michael M. Konnick, Brian M. Hashiguchi, Benjamin R. Black, Daniel H. Ess, Clinton R. King, Samantha J. Gustafson, Steven Kay Butler, Roy A. Periana
Publikováno v:
Organometallics. 36:109-113
M06 density functional theory calculations reveal that arene C–H functionalization by the p-block main-group-metal complex TlIII(TFA)3 (TFA = trifluoroacetate) occurs by a C–H activation mechanism akin to transition-metal-mediated C–H activatio
Publikováno v:
Structure and Bonding ISBN: 9783319316369
Alkane CH activation is a fundamental reaction class where a metal-ligand complex reacts with a CH bond to give a metal-alkyl organometallic intermediate. CH activation reactions have been reported for a variety of transition metals and main-group me
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::c9340f42cf418420d5440a249d99b90b
https://doi.org/10.1007/430_2015_178
https://doi.org/10.1007/430_2015_178
Autor:
Gerald D. Watt, Clinton R. King, Joseph L. Johnson, Jason Kenealey, Alisa J. Engan, P.E. Wilson, Thomas J. Lowery, Kyrsten Crawford, Andrew C. Nyborg
Publikováno v:
Biophysical Chemistry. 122:184-194
The molybdenum nitrogenase enzyme system, comprised of the MoFe protein and the Fe protein, catalyzes the reduction of atmospheric N(2) to NH(3). Interactions between these two proteins and between Fe protein and nucleotides (MgADP and MgATP) are cru