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Publikováno v:
Inorganic Chemistry. 40:5192-5198
The first Rh complex with an eta(4)-coordinated rac-et,ph-P4 ligand [et,ph-P4 = (Et2PCH2CH2)(Ph)PCH2P(Ph)(CH2CH2PEt2)] has been synthesized by reacting [Rh(nbd)2]BF4 with meso- or rac-et,ph-P4 in dichloromethane. The reaction occurs fairly rapidly at
Autor:
Frank R. Fronczek, Damon R. Billodeaux, George G. Stanley, Brent D. Nelson, Steven F. Watkins, Clinton Hunt, Elisa G. Harmon
Publikováno v:
Acta Crystallographica Section C Crystal Structure Communications. 56:546-548
Bis(μ-3,11-diethyl-6,8-diphenyl-3,6,8,11-tetraphosphatridecane-κ4P3,P6:P8,P11)dirhodium(I) bis(tetrafluoroborate), [Rh2(C25H40P4)2](BF4)2, is a bimetallic complex containing two binucleating tetra-tertiary phosphine ligands. The dista