Zobrazeno 1 - 10
of 11
pro vyhledávání: '"Cliff R. Baar"'
Autor:
Cliff R. Baar, Endy Y.-J Min, Lawrence M. Henling, John E. Bercaw, Michael W. Day, Christopher J. Levy
Publikováno v:
Journal of the American Chemical Society. 126:8216-8231
A series of enantiopure C_1-symmetric metallocenes, {(SiMe_2)_2[η^5-C_5H(CHMe_2)_2][η^5-C_5H_2((S)-CHMeCMe_3)]}ZrCl_2, (S)-2, {(SiMe_2)_2[η^5-C_5H(CHEt_2)_2][η^5-C_5H_2((S)-CHMeCMe_3)]}ZrCl_2, (S)-6, and {(SiMe_2)_2[η^5-C_5HCy_2][η^5-C_5H_2((S)
Publikováno v:
Organometallics. 20:3459-3465
Reaction of [PdMe2(μ-pyd)]2 (pyd = pyridazine) with the bis(bidentate) ligands R,R/S,S-trans-1,2-C6H10(NCH-2-C5H4N)2, 1, or C2H4(NCH-2-C5H4N)2, 2, gave the binuclear dimethylpalladium(II) complexes R,R/S/S-trans-1,2-[C6H10{NCH-2-C5H4N(PdMe2)}2], 3,
Autor:
Cliff R. Baar, Lee P. Carbray, and Michael C. Jennings, Richard J. Puddephatt, Jagadese J. Vittal
Publikováno v:
Organometallics. 20:408-417
Reaction of [PtMe2(μ-SMe2)]2 with cis-1,2-C6H10(NCH-2-C5H4N)2 (1) and cis-1,2-C6H10(NCH-2-C9H6N)2 (2) gives the complexes [PtMe2{cis-1,2-C6H10(NCH-2-C5H4N)2}] (3) and [PtMe2{cis-1,2-C6H10(NCH-2-C9H6N)2}] (4), respectively (C5H4N = pyridyl; C9H6N = q
Autor:
Hilary A. Jenkins, Richard J. Puddephatt, Cliff R. Baar, Michael C. Jennings, and Glenn P. A. Yap
Publikováno v:
Organometallics. 19:4870-4877
The chiral complexes [PtMe{cis-1-(NCHC6H4)-2-(NCHPh)C6H10}], 1, and [PtMe{trans-1-(NCHC6H4)-2-(NCHPh)C6H10}], 2, react with protic acids HBF4 or [H(OEt2)2][BAr4] (Ar = 3,5-(CF3)2C6H3) in the presence of olefin, with loss of methane, to give complexes
Publikováno v:
Organometallics. 19:4150-4158
Reaction of an excess of the ligand 1,2-C2H4(NCH-2-C5H4N)2 (1), 1,2-C2H4(NCH-2-C9H6N)2 (2), or 1,3-C3H6(NCH-2-C5H4N)2 (3) with [Pt2Me4(μ-SMe2)2] gives the following platinum(II) complexes that cont...
Publikováno v:
Organometallics. 19:2482-2497
The stereochemistry of oxidative addition of MeI and MeO3SCF3 to binuclear dimethylplatinum(II) complexes containing bis(bidentate) ligands such as cis- and trans-1,2-C6H10(NCH-2-C5H4N)2, 1 and 2a, has been studied. Oxidative addition of the Me−X b
Publikováno v:
Organometallics. 19:563-570
The complexes [PtMe2(DMEP)], 1, and [PtMe2(DMPP)], 2 [DMEP, DMPP = Me2N(CH2)nNCH-2-C5H4N, n = 2, 3, respectively], contain ligands that chelate to platinum through the imine and pyridyl groups, with the tertiary amine group not coordinated. Methyl io
Publikováno v:
Organometallics. 17:2805-2818
The ligands cis- and trans-1,2-(NCHC6H5)2C6H10 (trans, 1; cis, 2) underwent cyclometalation of one phenyl substituent on reaction with [Pt2Me4(μ-SMe2)2] (3) to give CH4 and chiral platinum(II) comp...
Publikováno v:
Organometallics. 17:32-40
The degree of stereoselectivity in intramolecular oxidative addition of aryl−halogen bonds to platinum(II) has been determined using the following diimine ligands based on trans- or cis-1,2-diamino...
Publikováno v:
Organometallics. 17:4329-4331