Zobrazeno 1 - 10
of 60
pro vyhledávání: '"Claus J. H. Jacobsen"'
Autor:
Nan-Yu Topsøe, Bjerne S. Clausen, Claus J. H. Jacobsen, Henrik Topsøe, Jens K. Nørskov, C.V. Ovesen
Publikováno v:
Bulletin des Sociétés Chimiques Belges. 104:283-291
Recently, we have shown that the periodic variations in the HDS activities of different transition metal sulfides can be explained by a Bond Energy Model (BEM) based on theoretically calculated metal sulfur bond energies. The model differs from many
Autor:
Claus J. H. Jacobsen, Thomas Willum Hansen, Michael Brorson, Astrid Boisen, Søren Dahl, Iver Schmidt
Publikováno v:
Technical University of Denmark Orbit
Nanomaterials are the building blocks of nanotechnology. Recently, nanotube materials have attracted considerable attention due to their unique physical and chemical properties. Here we discuss how nanotubes can be used as templates for preparation o
Publikováno v:
Materials Science Forum. :319-324
The calcination of the zeolite ZSM-5 was studied by in situ X-ray synchrotron powder diffraction. Two samples were studied: One conventionally synthesized (CONV) and one synthesized in a charcoal matrix according to the confined space synthesis metho
Autor:
Hans J. Jakobsen, Henrik Bildsøe, Tania Giavani, Jørgen Skibsted, Niels Blom, Kim Johannsen, Claus J. H. Jacobsen
Publikováno v:
Giavani, T, Johannsen, K, Jacobsen, C J H, Blom, N, Bildsøe, H, Skibsted, J & Jakobsen, H J 2003, ' Unusual observation of nitrogen chemical shift anisotropies in tetraalkylammonium halides by 14N MAS NMR spectroscopy ', Solid. State. Nucl. Mag., vol. 24, pp. 218-235 .
14N Magic-angle spinning (MAS) NMR spectra for a number of polycrystalline, symmetrical tetraalkylammonium halides with short alkyl chains (C2H(5)- to n-C4H(9)-) have been recorded following a careful setup of the experimental conditions. Analysis of
Autor:
Karoliina Honkala, Jens K. Nørskov, Claus J. H. Jacobsen, Siren Dahl, Ashildur Logadottir, Thomas Bligaard
Publikováno v:
Technical University of Denmark Orbit
For a class of heterogeneously catalyzed reactions, we explain the compensation effect in terms of a switching of kinetic regimes leading to a concomitant change in the apparent activation energy a...
Autor:
Hans J. Jakobsen, Claus J. H. Jacobsen, Ulla Gro Nielsen, Astrid Boisen, Jørgen Skibsted, Michael Brorson
Publikováno v:
Inorganic Chemistry. 41:6432-6439
Polycrystalline samples of AlVO(4) have been prepared by two methods of synthesis and characterized by (27)Al and (51)V MAS NMR spectroscopy at 14.1 T. The MAS NMR spectra clearly reveal that essentially pure samples with minor impurities of V(2)O(5)
Publikováno v:
Journal of Catalysis. 208:180-186
The kinetics of ammonia synthesis and N2 dissociation over cesium-promoted Co3Mo3N are studied. The results support recent DFT calculations and explain why Co3Mo3N shows a higher ammonia synthesis activity than either constituting metal. The ammonia
Publikováno v:
Catalysis Letters. 84:7-12
The catalytic activities of three supported, barium-promoted ruthenium catalysts for ammonia synthesis are reported. The three supports are silicon nitride (Si3N4), magnesium aluminum spinel (MgAl2O4), and graphitized carbon (C). The effect of the pr
Autor:
Claus J. H. Jacobsen, Jens K. Nørskov, Bjerne S. Clausen, Ashildur Logadottir, Astrid Boisen, Henrik Topsøe, Søren Dahl
Publikováno v:
Journal of Catalysis. 205:382-387
For ammonia synthesis catalysts a volcano-type relationship has been found experimentally. We demonstrate that by combining density functional theory calculations with a microkinetic model the position of the maximum of the volcano curve is sensitive
Publikováno v:
Applied Catalysis A: General. 222:19-29
The activity and selectivity of heterogeneous catalysts are determined by their electronic and structural properties. In many cases, the electronic properties are determined by the choice of both the catalytically active transition metal and promoter