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Selective synthesis of cyclooctanoids by radical cyclization of seven-membered lactones: neutron diffraction study of the stereoselective deuteration of a chiral organosamarium

Autor: Just-Baringo, Xavier, Clark, Jemma, Gutmann, Matthias, Procter, David

Publikováno v: Just-Baringo, X, Clark, J, Gutmann, M & Procter, D 2016, ' Selective synthesis of cyclooctanoids by radical cyclization of seven-membered lactones: neutron diffraction study of the stereoselective deuteration of a chiral organosamarium ', Angewandte Chemie-International Edition, vol. 55, no. 40 . https://doi.org/10.1002/anie.201606792

Seven-membered lactones undergo selective SmI2–H2O-promoted radical cyclization to form substituted cyclooctanols. The products arise from an exo-mode of cyclization rather than the usual endo-attack employed in the few radical syntheses of cyclooc

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https://www.research.manchester.ac.uk/portal/en/publications/selective-synthesis-of-cyclooctanoids-by-radical-cyclization-of-sevenmembered-lactones-neutron-diffraction-study-of-the-stereoselective-deuteration-of-a-chiral-organosamarium(1e63908b-f4f3-4ce9-94ae-9f70c43ed85f).html