Zobrazeno 1 - 10
of 27
pro vyhledávání: '"Clare, Bakewell"'
Publikováno v:
Inorganic Chemistry
The mechanism of the aluminum-mediated hydroboration of terminal alkynes was investigated using a series of novel aluminum amidinate hydride and alkyl complexes bearing symmetric and asymmetric ligands. The new aluminum complexes were fully character
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d9e387532ea29c72000391d8ae15eea5
https://doi.org/10.1021/acs.inorgchem.1c00619
https://doi.org/10.1021/acs.inorgchem.1c00619
Publikováno v:
Angewandte Chemie. 134
The design of new reductive routes to low oxidation state aluminium (Al) compounds offers the opportunity to better understand redox processes at the metal centre and develop reactivity accordingly. Here, a monomeric Al
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6acded513eb3b93f052ad8ff6a9965ec
https://doi.org/10.1002/ange.202205901
https://doi.org/10.1002/ange.202205901
Publikováno v:
Chemical Science
The synthesis and isolation of novel low oxidation state aluminium (Al) compounds has seen relatively slow progress over the 30 years since such species were first isolated. This is largely due to the significant challenges in isolating these thermod
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::fd5488fc30ee5456245028e4bbf73b8f
https://doi.org/10.1039/d0sc02686g
https://doi.org/10.1039/d0sc02686g
Autor:
Richard I. Cooper, Martí Garçon, Clare Bakewell, Alison J. Edwards, George A. Sackman, Mark R. Crimmin, Andrew J. P. White
Publikováno v:
Nature
Transition-metal complexes are widely used in the physical and biological sciences. They have essential roles in catalysis, synthesis, materials science, photophysics and bioinorganic chemistry. Our understanding of transition-metal complexes origina
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5c5d62e25cf4d6e84b86b7073cd5fe18
https://doi.org/10.1038/s41586-019-1616-2
https://doi.org/10.1038/s41586-019-1616-2
Publikováno v:
Chemical Science
The monomeric molecular aluminium(I) complex 1 [{(ArNCMe)2CH}Al] (Ar = 2,6-di-iso-propylphenyl) reacts with a series of terminal and strained alkenes including ethylene, propylene, allylbenzene and norbornene to form alkene bound products. Remarkably
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ccdffa68b01502a3ad3659ed8cc05633
https://doi.org/10.1039/c8sc04865g
https://doi.org/10.1039/c8sc04865g
Compiled by a new editorial team, this volume provides an invaluable resource covering many aspects of organometallic and coordination chemistry. The book has been developed through contributions from future leaders in organometallic chemistry at the
Autor:
Clare Bakewell
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 49(32)
The synthesis and characterisation of a series of magnesium complexes bearing sterically demanding amidinate ligands is reported; this includes magneisum amides (1a and 1b), hydrides (3a and 3b) and alkyl complexes (2b). The solid and solution state
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0bbc1e75d4920d3a83c47d3ce6daabf6
https://pubmed.ncbi.nlm.nih.gov/32766619
https://pubmed.ncbi.nlm.nih.gov/32766619
Publikováno v:
Journal of Chemical Research. 46:174751982210753
Silver (Ag) amidinate metal organic decomposition precursors of the type: [Ag2((ArN)2C(H))2] (Ar = 2,6-dimethylphenyl (1), 2,6-diethylphenyl (2) and 2,6-diisopropylphenyl (3)) have been used for the first time in the deposition of Ag films on glass w
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::507a78dcf8e84c0a8a5a9b5fe21cbde3
https://doi.org/10.1177/17475198221075301
https://doi.org/10.1177/17475198221075301
Autor:
Andrew J. P. White, Richard Y.C. Kong, Louisa O'Hare, Martí Garçon, Clare Bakewell, Mark R. Crimmin
The reactions of an aluminium(I) reagent with a series of 1,2-, 1,3- and 1,5-dienes are reported. In the case of 1,3-dienes the reaction occurs by a pericyclic reaction mechanism, specifically a cheletropic cycloaddition, to form aluminocyclopentene
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cf077a6688514eba3e42c509fbd0355c
https://doi.org/10.26434/chemrxiv.11400171.v1
https://doi.org/10.26434/chemrxiv.11400171.v1
Autor:
Martí, Garçon, Clare, Bakewell, George A, Sackman, Andrew J P, White, Richard I, Cooper, Alison J, Edwards, Mark R, Crimmin
Publikováno v:
Nature. 574(7778)
Transition-metal complexes are widely used in the physical and biological sciences. They have essential roles in catalysis, synthesis, materials science, photophysics and bioinorganic chemistry. Our understanding of transition-metal complexes origina
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::80e61e15f31fe829d994d495912b6b84
https://pubmed.ncbi.nlm.nih.gov/31597960
https://pubmed.ncbi.nlm.nih.gov/31597960