Zobrazeno 1 - 10
of 119
pro vyhledávání: '"Claire L, McMullin"'
Autor:
Kyle G. Pearce, Han-Ying Liu, Samuel E. Neale, Hattie M. Goff, Mary F. Mahon, Claire L. McMullin, Michael S. Hill
Publikováno v:
Nature Communications, Vol 14, Iss 1, Pp 1-5 (2023)
Abstract Counter to synthetic convention and expectation provided by the relevant standard reduction potentials, the chloroberyllate, [{SiNDipp}BeClLi]2 [{SiNDipp} = {CH2SiMe2N(Dipp)}2; Dipp = 2,6-i-Pr2C6H3)], reacts with the group 1 elements (M = Na
Externí odkaz:
https://doaj.org/article/bf8aa694578d45db8b74eaf53ae133dc
Autor:
Nathan Davison, Claire L. McMullin, Lu Zhang, Shu-Xian Hu, Paul G. Waddell, Corinne Wills, Casey Dixon, Erli Lu
Publikováno v:
Journal of the American Chemical Society. 145:6562-6576
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::16cc3314d6598773c9f4eb71dad68996
https://doi.org/10.1021/jacs.3c01033
https://doi.org/10.1021/jacs.3c01033
Autor:
Nathan Davison, James A. Quirk, Floriana Tuna, David Collison, Claire L. McMullin, Hannes Michaels, George H. Morritt, Paul G. Waddell, Jamie A. Gould, Marina Freitag, James A. Dawson, Erli Lu
Publikováno v:
Davison, N, Quirk, J, Tuna, F, Collison, D, Michaels, H, Morritt, G, Waddell, P, Gould, J, Freitag, M, Dawson, J 2022, ' A room-temperature-stable electride and its reactivity: Reductive benzene/pyridine couplings and solvent-free Birch reductions ', Chem, vol. 9 . https://doi.org/10.1016/j.chempr.2022.11.006
In this work, we report the synthesis of a room-temperature-stable electride (RoSE) reagent, namely K+(LiHMDS)e− (1) (HMDS: 1,1,1,3,3,3-hexamethyldisilazide), from accessible starting materials (potassium metal and LiHMDS) via mechanochemical ball
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::84239442e0ca1a86a6cc3f7d68396188
https://doi.org/10.1016/j.chempr.2022.11.006
https://doi.org/10.1016/j.chempr.2022.11.006
Publikováno v:
Chemical Science. 14:2866-2876
The C–Al bond of [{SiNDipp}Al–Cu(NHCiPr)] reacts sequentially with three equivalents of terminal alkyne to provide cuprous (hydrido)(alkynyl)aluminate, (E-alkenyl)(alkynyl)aluminate and bis(alkynyl)aluminate derivatives.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::aaba3274e92ecad77ce26192d56fc68d
https://doi.org/10.1039/d3sc00240c
https://doi.org/10.1039/d3sc00240c
Autor:
Han-Ying Liu, Samuel E. Neale, Michael S. Hill, Mary F. Mahon, Claire L. McMullin, Benjamin L. Morrison
Publikováno v:
Chemical Communications. 59:3846-3849
[{SiNDipp}MgNa]2 ({SiNDipp} = {CH2SiMe2N(Dipp)}2; Dipp = 2,6-i-Pr2C6H3) reacts directly with H2 in a process, which computational studies suggest, is dictated by the frontier MOs of both H2 and the low oxidation state s-block assembly.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::057488f5b90f4269444cb6c1f4f3b1e8
https://doi.org/10.1039/d3cc00710c
https://doi.org/10.1039/d3cc00710c
Autor:
Anne-Frédérique Pécharman, Annie L. Colebatch, Michael S. Hill, Claire L. McMullin, Mary F. Mahon, Catherine Weetman
Publikováno v:
Nature Communications, Vol 8, Iss 1, Pp 1-7 (2017)
Organoboranes are widely employed in organic synthesis and typically are prepared using electrophilic boron sources. Here the authors report a route to nucleophilic boryl anions via organomagnesium-driven cleavage of boron-boron bonds.
Externí odkaz:
https://doaj.org/article/e8659eb09b804bfb9bf50536728eb2fe
Autor:
Connie J. Isaac, Fedor M. Miloserdov, Anne-Frédérique Pécharman, John P. Lowe, Claire L. McMullin, Michael K. Whittlesey
Publikováno v:
Organometallics. 41:2716-2730
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e82e8cdd0543ac162b60ca47e84bcc48
https://doi.org/10.1021/acs.organomet.2c00344
https://doi.org/10.1021/acs.organomet.2c00344
Autor:
Thomas X. Gentner, Matthew J. Evans, Alan R. Kennedy, Sam E. Neale, Claire L. McMullin, Martyn P. Coles, Robert E. Mulvey
Publikováno v:
Gentner, T, Evans, M, Kennedy, A, Neale, S, McMullin, C, Coles, M & Mulvey, R 2022, ' Rubidium and caesium aluminyls: synthesis, structures and reactivity in C–H bond activation of benzene ', Chemical communications (Cambridge, England), vol. 58, no. 9, pp. 1390-1393 . https://doi.org/10.1039/D1CC05379E
Expanding knowledge of low valent aluminium chemistry, rubidium and caesium aluminyls are reported to complete the group 1 (Li–Cs) set of metal aluminyls. Both compounds crystallize as a contacted dimeric pair supported by M⋯π(arene) interaction
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f706ed6e0f846c1d9631a00c4e945fd1
https://doi.org/10.1039/d1cc05379e
https://doi.org/10.1039/d1cc05379e
Autor:
Matthew J. Evans, Mathew D. Anker, Claire L. McMullin, Samuel E. Neale, Nasir A. Rajabi, Martyn P. Coles
Publikováno v:
Chemical Science. 13:4635-4646
Reaction of Al–E (E = S, Se) multiple bonds with CO functionalities generates new C–E bonds.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::9bbda9ede8507c5d412cabeb6628ea2a
https://doi.org/10.1039/d2sc01064j
https://doi.org/10.1039/d2sc01064j
Autor:
Matthew J. Evans, George H. Iliffe, Samuel E. Neale, Claire L. McMullin, J. Robin Fulton, Mathew D. Anker, Martyn P. Coles
Publikováno v:
Chemical Communications. 58:10091-10094
We confirm that the μ-oxo species (NONDipp)Al(μ-O)M(BDIMes) are viable intermediates in the conversion of CO2 to carbonate promoted by bimetallic Al–Mg and Al–Zn compounds.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::8b4c7ab4ef99d07fee11784c7beb1252
https://doi.org/10.1039/d2cc04028j
https://doi.org/10.1039/d2cc04028j