Electronic and chiroptical properties of chiral cycloiridiated complexes bearing helicenic NHC ligands

Autor: Nora Hellou, Monika Srebro-Hooper, Marc Mauduit, Thierry Roisnel, Olivier Baslé, Christian Roussel, Nicolas Vanthuyne, Loïc Toupet, Claire Jahier-Diallo, Jochen Autschbach, Elsa Caytan, Jeanne Crassous

Publikováno v: Chemical Communications
Chemical Communications, 2016, 52 (59), pp.9243-9246. ⟨10.1039/C6CC04257K⟩
Chemical Communications, Royal Society of Chemistry, 2016, 52 (59), pp.9243-9246. ⟨10.1039/C6CC04257K⟩

International audience; The first helicene-NHC-iridium complexes have been prepared in enantiopure forms. Their stereochemical, electronic, and chiroptical features were characterized experimentally and via first-principles calculations, highlighting

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cb21f8fae6cd7b2828296d6e643b39b1
https://pubmed.ncbi.nlm.nih.gov/27354241

Multicomponent Synthesis of Chiral Bidentate Unsymmetrical Unsaturated N-Heterocyclic Carbenes: Copper-Catalyzed Asymmetric C Bond Formation

Autor: Mathieu Rouen, Christophe Crévisy, Olivier Baslé, Pierre Queval, Loïc Toupet, Marc Mauduit, Isabelle Artur, Pierre Querard, Claire Jahier-Diallo, Marie S. T. Morin

Publikováno v: Chemistry-A European Journal
Chemistry-A European Journal, Wiley-VCH Verlag, 2015, 21 (3), pp.993-7. ⟨10.1002/chem.201405765⟩
Chemistry-A European Journal, 2015, 21 (3), pp.993-7. ⟨10.1002/chem.201405765⟩

International audience; A multicomponent strategy was applied to the synthesis of chiral bidentate unsaturated hydroxyalkyl- and carboxyalkyl-N-heterocyclic carbene (NHC) precursors. The newly developed low-cost chiral ligands derived from amino alco

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::873b3bc2fdfa06793e4b3c09df77edae
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01114852