From a bulk solid to thin films of a hybrid material derived from the [Ti10O12(cat)8(py)8] oxo-cluster and poly(4-vinylpyridine)

Autor: Clément Chaumont, Laurent Barloy, Frederic Melin, Petra Hellwig, Bianca Patrahau, Pierre Mobian, Matthias Pauly, Marc Henry

Publikováno v: New Journal of Chemistry
New Journal of Chemistry, Royal Society of Chemistry, 2019, 43 (3), pp.1581-1588. ⟨10.1039/C8NJ05410J⟩
New Journal of Chemistry, 2019, 43 (3), pp.1581-1588. ⟨10.1039/C8NJ05410J⟩
New Journal of Chemistry, Royal Society of Chemistry, 2019, 43 (3), pp.1581-1588. ⟨10.1039/c8nj05410j⟩
New Journal of Chemistry, 2019, 43 (3), pp.1581-1588. ⟨10.1039/c8nj05410j⟩

International audience; In this work, we report the formation of a coloured inorganic–organic hybrid material generated from the [Ti10O12(cat)8(py)8] (catecholato (cat), pyridine (py)) oxo-cluster and poly(4-vinylpyridine). The titanium oxo-cluster

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::af4806d635526aef8cdd554924767ac7
https://hal.archives-ouvertes.fr/hal-02531882

An unprecedented high nuclearity catecholato-based Ti(iv)-architecture bearing labile pyridine ligands

Autor: Clément Chaumont, Pierre Mobian, Marc Henry

Publikováno v: Dalton Trans.. 43:3416-3419

We describe the synthesis and characterisation of a robust S4-symmetry titanium-based architecture bearing catecholato and pyridine ligands. This neutral complex formulated as [Ti10O12(cat)8(py)8] displays a tetrahedral inorganic core decorated by ca

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::561a025d4d7ff2bc68c920b7ab4d5a0b
https://doi.org/10.1039/c3dt53424c

Toward colored reticular titanium-based hybrid networks: Evaluation of the reactivity of the [Ti8O8(OOCCH2But)16] wheel with phenol, resorcinol and catechol

Autor: Clément Chaumont, Marc Henry, Clarisse Huguenard, E. Huen, Pierre Mobian

Publikováno v: Polyhedron. 57:70-76

The work presented here concerns the evaluation of the reactivity of the [Ti8O8(OOCCH2But)16] cluster towards phenol, resorcinol and catechol using NMR techniques. Whereas the reactions conducted in the presence of phenol and resorcinol showed to be

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::73e1f8f7c2573d8b842cdaeaf7a9da2d
https://doi.org/10.1016/j.poly.2013.04.021

Structural Investigation of Pyridinecarboxylato Titanium(IV) Complexes: An Uncommon Monomeric Octacoordinated Complex vs. a Hexaprismatic Architecture.

Autor: Fenton, Julie L.¹, Laaroussi, Anasse¹, Mobian, Pierre¹ mobian@unistra.fr, Chaumont, Clément¹, Khalil, Georges¹, Huguenard, Clarisse¹, Henry, Marc¹ henry@unistra.fr

Publikováno v: European Journal of Inorganic Chemistry. Jan2014, Vol. 2014 Issue 2, p357-363. 7p.

Titanium oxo-clusters derivatized from the Ti10O12(cat)8(py)8 complex: structural investigation and spectroscopic studies of light absorption.

Autor: Chaumont, Clément, Chaumont, Alain, Kyritsakas, Nathalie, Mobian, Pierre, Henry, Marc

Publikováno v: Dalton Transactions: An International Journal of Inorganic Chemistry; 6/7/2016, Vol. 45 Issue 21, p8760-8769, 10p