Zobrazeno 1 - 10
of 33
pro vyhledávání: '"Chunnian Shi"'
Autor:
Laurent Frémond, Fabien Burdet, Zhongping Ou, Chunnian Shi, Jean-Michel Barbe, Claude P. Gros, Jianguo Shao, Fred C. Anson, Roger Guilard, Karl M. Kadish
Publikováno v:
Journal of the American Chemical Society. 127:5625-5631
Three series of cobalt(III) corroles were tested as catalysts for the electroreduction of dioxygen to water. One was a simple monocorrole represented as (Me(4)Ph(5)Cor)Co, one a face-to-face biscorrole linked by an anthracene (A), biphenylene (B), 9,
Autor:
Chunnian Shi, Fred C. Anson
Publikováno v:
Inorganic Chemistry. 40:5829-5833
The electro-oxidation of cobalt (II) octaethylporphyrin adsorbed on graphite electrodes, Co^(II)(OEP)_(ads') to Co^(III)(OEP) ^+_(ads), in the presence of aqueous solutions of CO leads to catalytic oxidation of CO to CO_2. No such oxidation occurs wi
Autor:
Chunnian Shi and, Fred C. Anson
Publikováno v:
The Journal of Physical Chemistry B. 105:8963-8969
Rates of electron-transfer between redox reactants located on opposite sides of the interface between thin layers of organic solvents on graphite electrode and aqueous solutions were measured by means of steady-state electrochemistry. Changes in the
Publikováno v:
Polymers for Advanced Technologies. 12:266-270
A set of cobalt porphyrins containing alkyl substituents in their meso sites were synthesized and compared as catalysts for the electroreduction of O2 when adsorbed on the surface of graphite electrodes. The meso substituents examined included ethyl,
Autor:
Chunnian Shi, Fred C. Anson
Publikováno v:
Journal of Electroanalytical Chemistry. 484:144-149
The electroreduction of O 2 in two aprotic solvents (nitrobenzene and acetonitrile) was examined in the absence and in the presence of the very strong Lewis acid, triphenylmethyl cation, φ 3 C + (φ=phenyl). The addition of φ 3 C + causes the elect
Autor:
Fred C. Anson, Chunnian Shi and
Publikováno v:
The Journal of Physical Chemistry B. 103:6283-6289
A recently introduced method for interposing thin layers of organic solvents between graphite electrode surfaces and aqueous solutions was used to examine the effects of the nature and concentration of the supporting electrolytes on electrochemical r
Autor:
Chunnian Shi and, Fred C. Anson
Publikováno v:
The Journal of Physical Chemistry B. 102:9850-9854
A simple, new method is described that allows the rates of electron transfer across liquid/liquid interfaces to be measured with unprecedented ease. The method takes advantage of thin layers of organic liquids that adhere to the surface of pyrolytic
Autor:
Chunnian Shi, Fred C. Anson
Publikováno v:
Analytical Chemistry. 70:3114-3118
A method is described for the preparation of stable, adherent, thin layers of organic solvents interposed between the surfaces of graphite electrodes and aqueous supporting electrolytes in which they are immersed. The electrochemistry of reactants di
Publikováno v:
Langmuir. 14:4315-4321
Four cobalt porphyrins were adsorbed on graphite electrodes and used to catalyze the electroreduction of O2. The two porphyrins without substituent groups in the meso positions of the porphyrin ring operated at the most positive potentials and cataly
Autor:
Fred C. Anson, Chunnian Shi
Publikováno v:
Inorganic Chemistry. 37:1037-1043
Unlike most simple, monomeric cobalt porphyrins, the cobalt tetramethylporphyrin identified in the title catalyzes the electroreduction of O2 to H2O instead of H2O2. On graphite electrodes, coatings of the porphyrin prepared by irreversible adsorptio