Zobrazeno 1 - 4
of 4
pro vyhledávání: '"Christopher S. Gravatt"'
Publikováno v:
The Journal of organic chemistry. 87(14)
While trifluoromethylthiolation of aryl halides has been extensively explored, the current methods require complex and/or air-sensitive catalysts. Reported here is a method employing a bench-stable Ni(II) salt and an iridium photocatalyst that can me
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5a885cbdc37d670deeddd4e40a9fc018
https://pubmed.ncbi.nlm.nih.gov/35786936
https://pubmed.ncbi.nlm.nih.gov/35786936
Publikováno v:
Angew Chem Int Ed Engl
The sole method available for the photocycloaddition of unconjugated aliphatic alkenes is the Cu-catalyzed Salomon-Kochi reaction. The [Cu(OTf)]2 ⋅benzene catalyst that has been standard in this reaction for many decades, however, is air-sensitive,
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::20fdda62b2a4e3e590b5a8d3a1dcca83
https://doi.org/10.1002/anie.202013067
https://doi.org/10.1002/anie.202013067
While the area of trifluoromethylthiolation of aryl halides has been extensively explored, the current methods require complex and/or air-sensitive catalysts. Reported here is a method employing a bench-stable nickel(II) salt and an iridium photocata
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bc963fffdd89ad0b587684261d00b8e4
https://doi.org/10.26434/chemrxiv-2021-18xd5
https://doi.org/10.26434/chemrxiv-2021-18xd5
Publikováno v:
Organic letters. 19(2)
The incorporation of an easily oxidized arylsulfide moiety facilitates the photocatalytic generation of alkene radical cations that undergo a variety of cycloaddition reactions with electron-rich reaction partners. The sulfide moiety can subsequently
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::0c9161a389cb893c78a17d7418ccb729
https://pubmed.ncbi.nlm.nih.gov/28032508
https://pubmed.ncbi.nlm.nih.gov/28032508