Zobrazeno 1 - 8
of 8
pro vyhledávání: '"Christopher Rieker"'
Publikováno v:
Electrochimica Acta. 39:2367-2375
The redox behavior of three metallocene substituted (η 5 -cyclopentadienyl) (η 4 -1,3-cyclopentadien-5-exo-yl) cobalt complexes have the general formular [CpCo(η 4 −C 5 H 5 R)], where R = −CC -(η 5 −C 5 H 4 )FeCp (3), -(η 5 −C 5 H 4 )
Publikováno v:
Electrochimica Acta. 38:1527-1533
The results of an electrochemical study of two new π-bridged cobalt complexes [(η 5 -C 5 H 5 )Co{(η 4 -C 5 H 5 )-CC-(η 4 -C 5 H 5 )} ( 1 ) (η 5 -C 5 H 5 )Co&{(η 5 -C 5 H 4 )-CC-(η 5 -C 5 H 4 )}Co(η 5 -C 5 H 5 )] 2+ 2 PF − 6 ( 2 ) are
Publikováno v:
Journal of Electroanalytical Chemistry. 326:81-90
Electrochemical reduction of termetallocenes containing different kinds of metal atoms, [{(C5H5)M}2{η5:η5′- C10H8}2M′]n+ (n 1, M Fe, M′ Co; n 2, M Co, M′ Os, Ru), in a 0.1 M solution of Bu4N+PF6− in CH3CN leads to
Publikováno v:
Organometallics. 10:1293-1297
Electrochemical reduction of [(η 5 :η 5 '-C 10 H 8 ) 2 MCo] n+ (n=1, 2; M=Fe, Ru, Co) in a 0.1 M solution of Bu 4 N + PF 6 − in CH 3 CN at 20°C yields stable anions [(η 5 :η 5 '-C 10 H 8 ) 2 MCo] − (M=Fe, Ru, Co). In the case of M=Co, format
Autor:
Michael Wildschek, Christopher Rieker, Karl E. Schwarzhans, Peter Jaitner, Herwig Schottenberger
Publikováno v:
Journal of Organometallic Chemistry. 396:355-361
A general procedure for introducing substituents into cationic sandwich complexes by nucleophilic attack of suitable carbanions and subsequent hydride abstraction has been applied to the preparation of ethynyl-substituted cobaltocene species. Ethynyl
Publikováno v:
Journal of Organometallic Chemistry. 381:127-133
Convenient in situ preparations of ferrocenyl- and cobaltoceniumyl-cyclopentadienylide were achieved by two different synthetic routes. Ferrocenylcyclopentadienylide was prepared by lithiation of 1-(7-chlorobicyclo[2.2.1.]-hept-2-ene-7-yl)ferrocene.
Publikováno v:
Chemical Communications. :1245-1246
The novel oxo-centred tetrahedral cobalt cluster [Co 4 O] 6+ bridged by six carbamato ligands is prepared in high yield when reacting [Co 2 (CO) 8 ] with an excess of the nitroxyl radical 2,2,6,6-tetramethylpiperidin-1-oxyl; the molecular structure o
Publikováno v:
J. Chem. Soc., Chem. Commun.. :1800-1801
Novel polyselenides and polytellurides have been prepared by means of the stabilizing tris(trimetylsilyl)methyl group; [(Me3Si)3C]2Te3, the first compound containing a three tellurium atom chain, crystallizes as a trans-rotamer with a bonding angle o