Zobrazeno 1 - 10
of 20
pro vyhledávání: '"Christopher M. Kepert"'
Publikováno v:
Coordination Chemistry Reviews. 248:1329-1341
Ruthenium(II) complexes are finding applications in a variety of fields and, in particular, as photo-sensitisers in the conversion of solar energy into chemical or electrical energy where a major achievement has been the development of a dye sensitis
Publikováno v:
Inorganica Chimica Acta. 355:213-222
Addition of di(2-pyridyl)amine (dpa) to a solution formed by reaction of [Ru(CO) 2 Cl 2 ] n with NaOAc resulted in the precipitation of [Ru(OAc)(CO) 2 (dpa)] 2 , a complex containing a rare example of monodentate dpa coordination. X-ray crystallograp
Autor:
Christopher M. Kepert, B.O. West, Leone Spiccia, Stuart Robert Batten, Adrian M. B. van den Bergen, Paul S. Ammala
Publikováno v:
Inorganica Chimica Acta. 353:75-81
The reaction of [Fe4(μ3-O)2(O2CPh)8(py)2] (1) with Ti(OPrn)4 in toluene yields separate Fe and Ti species each containing both carboxylate and alkoxide groups rather than a bimetallic FeTi complex. The addition of neopentanol to the reaction mixt
Publikováno v:
Inorganic Chemistry. 42:5637-5644
Slow evaporation of solutions prepared by adding either Cu(ClO(4))(2).6H(2)O or Zn(ClO(4))(2).6H(2)O to solutions containing appropriate proportions of Me(3)tacn (1,4,7-trimethyl-1,4,7-triazacyclononane) and sodium phenyl phosphate (Na(2)PhOPO(3)) ga
Autor:
Christopher M. Kepert, Boujemaa Moubaraki, John D. Cashion, Leone Spiccia, B.O. West, Keith S. Murray, Stuart Robert Batten, Paul S. Ammala
Publikováno v:
Inorganica Chimica Acta. 331:90-97
The reaction of an Fe(III) oxo-benzoate species (1) with Al(OR)3 (R=Pri, Busec) yields the hexanuclear derivatives [Fe6(μ3-O)2(OR)8(O2CPh)6] (R=Pri (2); R=Busec (3)) which consist of planar Fe4(μ3-O)2 units, formed by two Fe3(μ3-O) groupings havin
Autor:
Christopher M. Kepert, Milton T.W. Hearn, Boujemaa Moubaraki, Leone Spiccia, Keith S. Murray, Bim Graham, Frank E Mabbs, Peter C. Junk
Publikováno v:
Inorganic Chemistry. 40:1536-1543
Hydroxo- and methoxo-bridged tetranuclear copper(II) complexes of the tetramacrocyclic ligand 1,2,4,5-tetrakis(1,4,7-triazacyclonon-1-ylmethyl)benzene (Ldur), have been prepared from [Cu4Ldur(H2O)8](ClO4)8.9H2O (1). Addition of base to an aqueous sol
Autor:
B.O. West, Keith S. Murray, Leone Spiccia, Paul S. Ammala, John D. Cashion, Boujemaa Moubaraki, Christopher M. Kepert
Publikováno v:
Journal of the Chemical Society, Dalton Transactions. :2032-2041
Reaction of [Fe3(μ3-O)(O2CPh)6(H2O)3](O2CPh) with pyridine yields a product (2) which on recrystallisation rearranges to [Fe6(μ-O)2(μ-OH)2(O2CPh)12(py)2] (3). Magnetic and Mossbauer spectral analyses suggest that compound (2) contains an Fe4(O)2 c
Publikováno v:
Journal of the Chemical Society, Dalton Transactions. :2232-2238
A structural and electrochemical study of the nickel(II) complexes, [Ni(tacn)2](ClO4)2 (1), [NiLeth](ClO4)2 (2), [NiLox](ClO4)2·H2O (3), [Ni2Ldur](ClO4)4·2H2O (4), [Ni3Ldur(H2O)3](ClO4)6·9H2O (5) and [Ni2Lisomes(H2O)3](ClO4)4·7H2O (6) [tacn = 1,4
Autor:
Brian W. Skelton, M J Grannas, Allan H. White, Bimbil Graham, Milton T.W. Hearn, Leone Spiccia, Christopher M. Kepert
Publikováno v:
Inorganic Chemistry. 39:1092-1099
A new polynucleating ligand, 1,2,4,5-tetrakis(1,4,7-triazacyclonon-1-ylmethyl)benzene (Ldur), has been prepared and characterized as its dodecahydrobromide salt. Addition of base to an aqueous solution of this salt and 4 molar equivalents (m.e.) of a
Autor:
Brian W. Skelton, Allan H. White, Christopher M. Kepert, Leone Spiccia, Glen B. Deacon, Gary D. Fallon
Publikováno v:
Monash University
Polymeric dicarbonyldichlororuthenium(II) [Ru(CO)2Cl2]n is reduced by reaction with carboxylate salts (RCO2−Na+) in alcoholic suspension. Dimeric ruthenium(I) “sawhorse” complexes [Ru(RCO2)(CO)2L]2 (R = Me, Et, But, Ph) are formed on the additi