Zobrazeno 1 - 10
of 30
pro vyhledávání: '"Christopher M. Barshick"'
Publikováno v:
Applied Spectroscopy. 53:65-73
Tetrafluoromethane (CF4, 1.01% by weight) was added to the argon support gas of a hollow cathode glow discharge to investigate the analytical utility of etch atomization. When a conducting copper cathode was analyzed, the sputtering rate (as measured
Publikováno v:
Analytical Chemistry. 71:483-488
Isotope dilution has been applied to an approach recently developed to quantify inorganic mercury compounds by ion trap gas chromatography/mass spectrometry (GC/MS). In this approach, a chemical al...
Publikováno v:
Analytical Chemistry. 70:709A-717A
Ion traps represent a radical change in thinking and a unique opportunity for the elemental mass spectrometrist to utilize these unique capabilities.
Autor:
Elisabeth B Walsh, Stacy-Ann Barshick, Michael A. Vance, Phillip F. Britt, Christopher M. Barshick, Derek A Lake
Publikováno v:
International Journal of Mass Spectrometry. 178:31-41
A technique has been developed to analyze environmentally relevant samples for organic and inorganic mercury compounds. A solid phase microextraction (SPME) fiber was used as a sampling medium in both water and water/soil slurries. Quantification of
Publikováno v:
International Journal of Mass Spectrometry. 178:73-79
The combination of a glow discharge ionization source with a Fourier transform ion cyclotron resonance (FTICR) mass spectrometer provides several advantages for elemental analysis; among these is an isotope ratio measured at the highest possible mass
Publikováno v:
Microchemical Journal. 55:208-221
This paper reports on novel efforts to prepare standard materials for glow discharge mass spectrometric (GDMS) applications by electrolytically depositing trace quantities of transition metal ions onto the surface of a compressed silver electrode. Th
Autor:
Christopher M. Barshick, Matthew L. Mohill, Phillip F. Britt, David H. Smith, Stacy-Ann Barshick
Publikováno v:
Rapid Communications in Mass Spectrometry. 10:341-346
Glow discharge mass spectrometry (GDMS) and gas chromatography/mass spectrometry (GC/MS) have been evaluated as techniques for total elemental assay in soil. GDMS analysis demonstrated accurate elemental quantification for lead and tin (approximately
Publikováno v:
Rapid Communications in Mass Spectrometry. 10:316-320
Publikováno v:
Analytical Chemistry. 67:3814-3818
The measurement precision and accuracy were evaluated for an isotopic analysis of uranium using diode laser-excited optogalvanic spectroscopy. The ratio of 235 U/( 235 U + 238 U) was measured using the 776 nm uranium isotope line for five samples ran
Autor:
Fred L. King, David H. Smith, Douglas C. Duckworth, Shelby J. Morton, Christopher M. Barshick, Jiuwei Teng
Publikováno v:
Applied Spectroscopy. 49:1361-1366
The influence of oxygen content, conducting host matrix, and soil composition on the quantitative determination of trace elements in soils by glow discharge mass spectrometry was examined. Oxygen content and conducting host matrix identity influenced