Zobrazeno 1 - 10
of 25
pro vyhledávání: '"Christopher J. Evenhuis"'
Publikováno v:
Analytical Chemistry. 83:1808-1814
Temperature increase in capillary electrophoresis (CE) due to Joule heating is an inherent limitation of this powerful separation technique. Active cooling systems can decrease the temperature of a large part of the capillary but they leave "hot spot
Publikováno v:
Journal of Separation Science. 34:556-564
We coin a term of milli-free flow electrophoresis (mFFE) to describe mid-scale FFE with flow rates intermediate to macro-FFE and micro-FFE (μFFE). Introduced decades ago, mFFE did not find practical applications. We revive mFFE, as we view it as a v
Publikováno v:
Analytical Chemistry. 82:8398-8401
Electro-migration techniques, such as electrophoresis, are widely utilized in analytical sciences. If a single electrolyte is used, the field strength is typically assumed to be well-defined. Heat-associated field distortion (HAFD) has been suggested
Publikováno v:
Analytica Chimica Acta. 674:102-109
Micro-free flow electrophoresis (microFFE) is a technique that facilitates continuous separation of molecules in a shallow channel with a hydrodynamic flow and an electric field at an angle to the flow. We recently developed a general theory of micro
Publikováno v:
TrAC Trends in Analytical Chemistry. 28:987-1010
A capillary or a narrow channel is an attractive medium for studying reactions. A capillary can serve as (i) a microreactor for carrying out a reaction in a nanoliter volume and (ii) a separation column to separate the reaction products prior to thei
Autor:
Christopher J. Evenhuis, Kelly Flook, Pavel N. Nesterenko, Emily F. Hilder, Christopher A. Pohl, Wolfgang Buchberger, Paul R. Haddad
Publikováno v:
Journal of Separation Science. 31:2598-2604
A commercially available 4.6 mm. id × 50 mm polymethacrylate-based monolithic strong anion exchange column (ProSwift™ SAX-1S) designed for the separation of proteins has been successfully used to separate small inorganic anions in the presence of
Publikováno v:
ELECTROPHORESIS. 28:3477-3484
In this work, a new generation UV-transparent polymer, fluorinated ethylenepropylene copolymer (FEP) exhibiting a low degree of crystallinity, extruded in dimensions similar to the most commonly used CE capillaries of approximately 80 mum id and abou
Autor:
Philip J. Marriott, Christopher J. Evenhuis, Rosanne M. Guijt, Bohuslav Gaš, Paul R. Haddad, Miroslav Macka, Vlastimil Hruška
Publikováno v:
ELECTROPHORESIS. 28:3759-3766
Ionic electrophoretic mobilities determined by means of CE experiments are sometimes different when compared to generally accepted values based on limiting ionic conductance measurements. While the effect of ionic strength on electrophoretic mobility
Publikováno v:
Electroanalysis. 18:1289-1296
The analytical performance parameters of four different contactless conductivity detectors for capillary electrophoresis were determined. These detectors were designed either with a miniature cell for versatility, with high voltage excitation for hig
Autor:
Paul R. Haddad, Christopher J. Evenhuis, Rosanne M. Guijt, Miroslav Macka, Philip J. Marriott
Publikováno v:
ELECTROPHORESIS. 26:4333-4344
Polymers are important as materials for manufacturing microfluidic devices for electrodriven separations, in which Joule heating is an unavoidable phenomenon. Heating effects were investigated in polymer capillaries using a CE setup. This study is th