Zobrazeno 1 - 10
of 24
pro vyhledávání: '"Christophe Nedez"'
Publikováno v:
Comptes Rendus Chimie. 7:785-796
Thermolysis of the organometallic complex SiOSn(n-C4H9)3 1 grafted on silica dehydroxylated either at 200 (silica(200)) or 500 °C (silica(500)) can be interpreted by assuming two decomposition pathways: (i) hydrolysis of the butyl groups by silan
Autor:
Xu Xu Wang, Mariko Adachi, Frédéric Lefebvre, François Bayard, Christophe Nedez, Jean-Marie Basset, Véronique Dufaud
Publikováno v:
Journal of Molecular Catalysis A: Chemical. :443-455
The organometallic complex SiOZr(CH2C(CH3)3)3 was synthesized on the surface of silica dehydroxylated at 500 °C and its reactivity towards oxygenated molecules was studied. The materials were characterized by IR, 13 C CP-MAS NMR, analysis o
Autor:
E. Laperdrix, Christophe Nedez, Jean Claude Lavalley, Abdelaziz Sahibed-Dine, Guylène Costentin, Odette Saur, A.B. Mohamed Saad, Mohammed Bensitel
Publikováno v:
Applied Catalysis B: Environmental. 26:71-80
Sulfate species formed by heating SO2 in excess of O2 at 723 K on TiO2, ZrO2, Al2O3 and Al2O3 promoted by Fe, Cu, Ni, Mo, W or V were studied by FT-IR spectroscopy. The presence of Ni, Cu or Fe enhance sulfate formation on the alumina support. The su
Autor:
J. Nougayrède, Odette Saur, Guylène Costentin, E. Laperdrix, S. Savin-Poncet, Christophe Nedez, Jean-Claude Lavalley
Publikováno v:
Journal of Catalysis. 189:63-69
A CuO/Al 2 O 3 catalyst was used for selective oxidation of hydrogen sulfide into sulfur at low temperature (383 K). H 2 S is totally consumed during the 28 first hours of the reaction, without detection of SO 2 nor S n . The decrease of H 2 S conver
Publikováno v:
Catalysis Reviews. 40:409-450
This review article deals with the development of sulfur recovery from the Claus process to H2S selective oxidation. Governments are constantly tightening regulations to limit the emission of sulfur compounds into the air. This makes it necessary to
Autor:
Christophe Nedez, A Aboulayt, Odette Saur, J.L Ray, Jean-Claude Lavalley, Guylène Costentin, I Justin, E. Laperdrix
Publikováno v:
Applied Catalysis B: Environmental. 17:167-173
The study is devoted to the comparison between the activity of γ-alumina and titania (anatase) toward CS2 hydrolysis. It is shown that, without any other sulfur compound, like H2S and SO2, and without O2 traces in the feed, alumina is more active th
Publikováno v:
Journal of the Chemical Society, Faraday Transactions. 93:1987-1992
The thermolysis of Si–O–SnMe 3 grafted onto partially dehydroxylated silicas has been studied by in situ IR, 13 C CP MAS NMR and TPD. The only detected gaseous product was methane, showing that the thermolysis process passes through a simple hydr
Autor:
Christophe Nedez, Jean-Louis Ray
Publikováno v:
Catalysis Today. 29:139-142
We have developed a new Claus alumina which presents a particular ultramacroporosity, between 0.1 and 1 μm (to reduce diffusional constraints) and a well-defined soda content (below 2500 ppm Na 2 O) to reduce the sulfation of the surface and, thus,
Autor:
Christophe Nedez, Jean-Louis Ray
Publikováno v:
Catalysis Today. 27:49-53
The discovery of two new concepts have made it possible to draw the physico-chemical map of the best alumina Claus catalyst. An optimized profile of the ultramacroporosity, between 0.1 and 1 μm, reduces diffusional constraints. A low sodium (Na 2 0)
Publikováno v:
J. Chem. Soc., Faraday Trans.. 92:3419-3423
The thermal transformation in vacuo of the well defined surface organometallic fragments [AlO]xSn(n-C4H9)3(x= 1,2) 1 grafted on various partially dehydroxylated aluminas (α, γ, η) has been investigated. The surface reactions were followed by quali