Statistical Analysis of Copper(I) Iodide and Bis(Diphenylphosphino)alkane-Based Complexes and Coordination Polymers

Autor: Léo Boivin, Adrien Schlachter, Daniel Fortin, Christophe Lescop, Pierre D. Harvey

Publikováno v: Molecules, Vol 28, Iss 23, p 7781 (2023)

The prediction of the metal cluster within a coordination polymer or complex, as well as the dimensionality of the resulting polymer or complex (i.e., 0D, 1D, 2D, or 3D), is often challenging. This is the case for Ph2P(CH2)mPPh2 ligands (1 ≤ m ≤

Externí odkaz: https://doaj.org/article/17b989e5945743f38e377fcbb64d3e96

Intramolecular rearrangements guided by adaptive coordination-driven reactions toward highly luminescent polynuclear Cu(i) assemblies

Autor: Karine Costuas, Sloane Evariste, Vivian Wing-Wah Yam, Ali Moustafa Khalil, Mehdi Elsayed Moussa, Guillaume Calvez, Christophe Lescop, Vincent Delmas, Boris Le Guennic, Hok-Lai Wong

Publikováno v: Inorganic Chemistry Frontiers
Inorganic Chemistry Frontiers, Royal Society of Chemistry, 2020, 7 (6), pp.1334-1344. ⟨10.1039/c9qi01595g⟩
Inorganic Chemistry Frontiers, 2020, 7 (6), pp.1334-1344. ⟨10.1039/c9qi01595g⟩

International audience; Adaptive coordination-driven supramolecular chemistry based on conformationally flexible pre-organized luminescent Cu(I) precursors paves the way to the ready formation of intricate supramolecular scaffold possessing intrinsic

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b85d5856d958df6897a0a8cfdf5e4122
https://doi.org/10.1039/c9qi01595g

Structural and Luminescence Properties of Anthracene- and Biphenyl-Based Lanthanide Bisphosphonate Ester Coordination Polymers

Autor: Guillaume Calvez, Christophe Lescop, Kristijan Krekić, Rudolf Pietschnig, Dieter Klintuch

Publikováno v: Inorganic Chemistry
Inorganic Chemistry, American Chemical Society, 2019, 58 (1), pp.382-390. ⟨10.1021/acs.inorgchem.8b02502⟩
Inorganic Chemistry, 2019, 58 (1), pp.382-390. ⟨10.1021/acs.inorgchem.8b02502⟩

Coordinative networks containing lanthanide ions attached via phosphonate ester functionalities provide remarkable luminescence properties. On the basis of ditopic phosphonic ester ligands with biphenylene and 9,10-anthracenylene bridges, a series of

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::f3d49b624fc58587c25c082b5b7e2789
https://doi.org/10.1021/acs.inorgchem.8b02502

Straightforward coordination-driven supramolecular chemistry preparation of a discrete solid-state luminescent Cu4 polymetallic compact assembly based on conformationally flexible building blocks

Autor: Sloane Evariste, Chendong Xu, Guillaume Calvez, Christophe Lescop

Publikováno v: Inorganica Chimica Acta
Inorganica Chimica Acta, Elsevier, 2021, 516, pp.120115. ⟨10.1016/j.ica.2020.120115⟩
Inorganica Chimica Acta, 2021, 516, pp.120115. ⟨10.1016/j.ica.2020.120115⟩

International audience; The ditopic nitrile-capped 1,4-phenylenediacetonitrile linker L3 featuring partial conformational flexibility was reacted with a flexible pre-assembled Cu(I) dimer stabilized by the bis(diphenyl-phosphino)methane dppm ligand a

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d050a24488bed9be3512a6c1b252fe96
https://hal.archives-ouvertes.fr/hal-03130407/document

Luminescent vapochromic single crystal to single crystal transition in one-dimensional coordination polymer featuring the first Cu(i) dimer bridged by an aqua ligand

Autor: Sebastien Kerneis, Karine Costuas, Ali Moustafa Khalil, Chendong Xu, Guillaume Calvez, Christophe Lescop, Sloane Evariste

Publikováno v: Inorganic Chemistry Frontiers
Inorganic Chemistry Frontiers, 2020, 7 (18), pp.3402-3411. ⟨10.1039/d0qi00691b⟩
Inorganic Chemistry Frontiers, Royal Society of Chemistry, 2020, 7 (18), pp.3402-3411. ⟨10.1039/d0qi00691b⟩

International audience; The reaction of the pre-assembled bimetallic Cu(i) [Cu-2(mu(2)-dppm)(2)](2+) fragment with the ligand 1,4-dicyanobenzeneB(0)in non-distilled CH(2)Cl(2)allowed the characterisation of an unexpected one-dimensional coordination

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::956a66d4afa16dfb7485dcfc30b9cbe7
https://hal.science/hal-02957759/file/draft-inorg-chem-front-rev-unmarked.pdf