Zobrazeno 1 - 10
of 10
pro vyhledávání: '"Christoph Stuhl"'
Autor:
Verena M. Birkelbach, Felix Kracht, Cäcilia Maichle-Mössmer, Reiner Anwander, H. Martin Dietrich, Christoph Stuhl
Publikováno v:
Organometallics. 39:3490-3504
Treatment of the half-sandwich complexes CpRLn(AlMe4)2 (CpR = C5Me5, C5Me4SiMe3; Ln = Y, La, Lu) with the mild halogenido transfer reagents SiMe3X (X = Cl, Br, I) resulted in efficient and selectiv...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::41ce7d8af77e0a497d53d057694a7293
https://doi.org/10.1021/acs.organomet.0c00447
https://doi.org/10.1021/acs.organomet.0c00447
Autor:
Cäcilia Maichle-Mössmer, Martin Bonath, Christoph Stuhl, Verena M. Birkelbach, Reiner Anwander
Publikováno v:
Chemical communications (Cambridge, England). 57(64)
Thermal treatment of Cp*2YMe(thf) (Cp* = C5Me5), obtained from Cp*2Y(AlMe4) via donor-induced AlMe3 cleavage, in THF resulted in the concomitant formation of vinyl oxide Cp*2Y(OC2H3)(thf) and 2-ethylene-tetrahydrofuranyl complex Cp*2Y(2-C2H4-OC4H7) v
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1525a33e4edf7d15b6ce6e2d03c6aa17
https://pubmed.ncbi.nlm.nih.gov/34286733
https://pubmed.ncbi.nlm.nih.gov/34286733
Publikováno v:
Organometallics. 38:4485-4496
Various mixed methyl aryloxide complexes TptBu,MeLnMe(OAr) (Ln = Y, Lu) were obtained in moderate to high yields according to distinct synthesis protocols dependent on the metal size and sterics of...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::a77ccb3ced21231201fd4bdb281daf64
https://doi.org/10.1021/acs.organomet.9b00631
https://doi.org/10.1021/acs.organomet.9b00631
Publikováno v:
Chemistry (Weinheim an Der Bergstrasse, Germany)
A series of solvent‐free heteroleptic terminal rare‐earth‐metal alkyl complexes stabilized by a superbulky tris(pyrazolyl)borato ligand with the general formula [TptBu,MeLnMeR] have been synthesized and fully characterized. Treatment of the het
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9d5006f7b1f787cf5174da4eba6d6232
https://doi.org/10.1002/chem.201903606
https://doi.org/10.1002/chem.201903606
Publikováno v:
Organometallics. 38:1614-1621
A series of heteroleptic calcium complexes supported by the superbulky scorpionate ligand tris(3-tBu-5-Me-pyrazolyl)borato (TptBu,Me) was synthesized and characterized comprehensively. Tetramethyla...
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::343dc3ff3f9cc256a5bb2f0fc035fefc
https://doi.org/10.1021/acs.organomet.9b00047
https://doi.org/10.1021/acs.organomet.9b00047
Autor:
Verena M. Birkelbach, H. Martin Dietrich, David Schneider, Cäcilia Maichle-Mössmer, Reiner Anwander, Christoph Stuhl, Karl W. Törnroos, Dennis A. Buschmann
Publikováno v:
Chemistry-A European Journal
Chemistry (Weinheim an Der Bergstrasse, Germany)
Chemistry (Weinheim an Der Bergstrasse, Germany)
Tetramethylaluminato/halogenido(X) ligand exchange reactions in half‐sandwich complexes [CpRLa(AlMe4)2] are feasible in non‐coordinating solvents and provide access to large coordination clusters of the type [CpRLaX2]x. Incomplete exchange reacti
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::19b62f023cbd011f05ec185a1bba7627
https://pubmed.ncbi.nlm.nih.gov/32329535
https://pubmed.ncbi.nlm.nih.gov/32329535
Publikováno v:
Journal of the American Chemical Society. 140:2373-2383
The salt metathesis reaction between homoleptic calcium bis(trimethylsilyl)amide [Ca{N(SiMe
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8b47a5987d2aa58c12110356f38c66bb
https://doi.org/10.1021/jacs.7b12984
https://doi.org/10.1021/jacs.7b12984
Publikováno v:
Dalton transactions (Cambridge, England : 2003). 47(42)
Treatment of dimethylmagnesium with dimethylaluminum hydride in common ethereal solvents led to the bimetallic monomagnesium addition compounds [(do)xMg{(μ2-H)(AlMe3)}2] (do = thf, x = 4, do = Et2O, x = 3; do = dme, x = 2). Utilization of methyl ter
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::d47ee9e92ff20fc34f38d9ca5958bb56
https://pubmed.ncbi.nlm.nih.gov/30318539
https://pubmed.ncbi.nlm.nih.gov/30318539
Publikováno v:
Chemical communications (Cambridge, England). 54(64)
The reaction of LnI2(thf)2 with benzyl potassium affords the homoleptic benzyl complexes [Ln(CH2Ph)2]n of samarium, europium, and ytterbium. In the cases of Eu and Yb, the treatment of [Ln(CH2Ph)2]n with one equivalent of 2,6-diisopropylaniline gives
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::bd5e914eaf47b74a11341001e208ed83
https://pubmed.ncbi.nlm.nih.gov/30043800
https://pubmed.ncbi.nlm.nih.gov/30043800
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 24(53)
A series of tris(pyrazolyl)alkane (RCTp) scorpionate ligands of the type RCTp3-R' (R=Me, nBu, SiMe3 ; R'=H, Me, Ph, iPr, tBu) were synthesized and their ability to coordinate methylmagnesium moieties was examined. The reaction of Mg(AlMe4 )2 with neu
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a57ad321fb1d9b6756162c5ac3d7b15d
https://pubmed.ncbi.nlm.nih.gov/29993157
https://pubmed.ncbi.nlm.nih.gov/29993157