Zobrazeno 1 - 10
of 123
pro vyhledávání: '"Christoph Sämann"'
Publikováno v:
Organic Letters. 16:2418-2421
The LiCl-mediated Mg-insertion in the presence of ZnCl2 allows an efficient synthesis of adamantylzinc reagents starting from the corresponding functionalized tertiary bromides. The highly reactive adamantylzinc species readily undergo a broad variet
Publikováno v:
The Journal of Organic Chemistry. 79:4253-4269
Polyfunctional zinc and magnesium organometallic reagents occupy a central position in organic synthesis. Most organic functional groups are tolerated by zinc organometallic reagents, and Csp(2)-centered magnesium organometallic reagents are compatib
Publikováno v:
Angewandte Chemie. 126:1454-1458
Eine einfache und flexible Methode fur die selektive Funktionalisierung aller Positionen des Imidazolrings durch regioselektive Arylierungen, Allylierungen, Acylierungen und Additionen an Aldehyde ist entwickelt worden. Ausgehend von dem leicht herzu
Publikováno v:
Angewandte Chemie International Edition. 53:1430-1434
A simple, flexible, and straightforward method for the functionalization of all the positions of the imidazole heterocycle through regioselective arylations, allylations, acylations, and additions to aldehydes is disclosed. Starting from the readily
Publikováno v:
Zeitschrift für Naturforschung B. 68:411-422
This review describes the various ways of functionalizing the pyridine scaffold using either directed metalation or halogen/metal exchange. Deprotonation can be accomplished with different lithium amides or alkyllithium reagents at low temperature. M
Publikováno v:
Angewandte Chemie. 125:9673-9677
Publikováno v:
Angewandte Chemie International Edition. 52:9495-9499
Autor:
Christoph Sämann, Paul Knochel
Publikováno v:
Synthesis. 45:1870-1876
A practical and convenient procedure for the synthesis of α-substituted β,γ-unsaturated ketones and esters has been developed. Substituted allylic zinc reagents, prepared via direct metal insertion in substituted allylic halides, react readily wit
Publikováno v:
Angewandte Chemie. 123:7428-7432
Publikováno v:
Angewandte Chemie International Edition. 50:7290-7294