Zobrazeno 1 - 10
of 24
pro vyhledávání: '"Christoph J. Rohbogner"'
Autor:
Paul Knochel, Matthias A. Schade, Sebastian Bernhardt, Georg Manolikakes, Albrecht Metzger, Fabian M. Piller, Christoph J. Rohbogner, Marc Mosrin
Publikováno v:
Beilstein Journal of Organic Chemistry, Vol 7, Iss 1, Pp 1261-1277 (2011)
In this review we summarize the most important procedures for the preparation of functionalized organzinc and organomagnesium reagents. In addition, new methods for the preparation of polyfunctional aryl- and heteroaryl zinc- and magnesium compounds,
Externí odkaz:
https://doaj.org/article/2c5fa8f8138e450e8cee7899a5a7d5e0
Autor:
Uwe Käfer, Daniel Struckmeier, Thomas Wilharm, Ralf Zimmermann, Thomas Gröger, Mohammad R. Saraji-Bozorgzad, Christoph J. Rohbogner
Publikováno v:
Energy & Fuels. 33:10745-10755
On January 1, 2020, new International Maritime Organization (IMO) legislation will reduce the maximum sulfur content for marine fuels outside of sulfur emission control areas (SECA) from now 3.50% ...
Publikováno v:
Advanced Synthesis & Catalysis. 355:1553-1560
A convenient and efficient functionalization of polyhaloaromatics via regioselective magnesiation has been developed. Starting from simple, inexpensive but structurally challenging arenes, metallation by magnesium amide bases was achieved under mild
Publikováno v:
Angewandte Chemie. 122:1918-1921
Publikováno v:
Organic Process Research & Development. 14:339-345
A range of aryl and heteroaryl organometallics are efficiently prepared in THF via directed ortho metalation by using the previously reported amide bases tmpMgCl·LiCl (tmp = 2,2,6,6-tetramethylpiperidyl), tmp2Mg·2LiCl and tmp2Zn·2MgCl2·2LiCl. The
Publikováno v:
European Journal of Organic Chemistry. 2009:1781-1795
New mixed Li/Mg and Li/Mg/Zn amides have been synthesized starting from readily prepared secondary amines. They allow a highly chemoselective directed magnesiation or zincation of various polyfunctional aromatics and heteroaromatics. The kinetic basi
Publikováno v:
Angewandte Chemie. 120:1526-1530
Publikováno v:
Angewandte Chemie. 119:7825-7828
Publikováno v:
ChemInform. 44
The regioselective magnesiation of haloarenes (I) and (XI) followed by reaction of the resulting Grignard reagents with different electrophiles provides access to a variety of functionalized polyhaloarenes.
Publikováno v:
Organic letters. 13(12)
A new Fe- or Co-catalyzed Cl/Zn-exchange reaction allows the direct transformation of aryl, heteroaryl, and also alkyl chlorides into the corresponding zinc reagents. The method tolerates functional groups such as a nitrile or an ester. Remarkably, s