Zobrazeno 1 - 10
of 174
pro vyhledávání: '"Christoph Elschenbroich"'
Publikováno v:
European Journal of Inorganic Chemistry. 2015:2883-2888
Group 15 P-atom-bridged paramagnetic unsymmetric sandwich binuclear di([5]trovacenyl)phenylphosphane (2··) was prepared and characterized by mass spectroscopy, elemental analysis, and X-ray diffraction analysis (XRD). The investigation of 2·· by
Publikováno v:
Polyhedron. 79:300-305
A new paramagnetic termetallocene, di([5]trovacenyl-tetramethyl-η5-cyclopentandienyl)iron (3 ), has been prepared via the reaction of [5]trovacenyllithium with 2,3,4,5-tetramethylcyclopenten-1-one, followed by hydrolysis with water, lithiation with
Publikováno v:
Journal of Organometallic Chemistry. 755:58-63
Organometallic paramagnetic [5]trovacenylthiol (3 ) was prepared by acidification of lithium [5]trovacenylthiolate 2 , which was synthesized via elemental sulfur oxidative insertion to C–Li bond of [5]trovacenyllithium. [5]Trovacenylthiol (3 ) was
Autor:
Feng Lu, Christoph Elschenbroich, Olaf Burghaus, Clemens Pietzonka, Jürgen Pebler, Klaus Harms
Publikováno v:
European Journal of Inorganic Chemistry. 2012:3929-3936
The oligosulfur-bridged dinuclear paramagnetic complexes di([5]trovacenyl) sulfide (3··), di([5]trovacenyl) trisulfide (5··), di([5]trovacenylthio)methane (6··), and di([5]trovacenyl) tetrasulfide (7··) have been prepared by the metathesis re
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 637:1750-1755
The paramagnetic bis(5trovacenyl)dichalcogenides(η7-C7H7)V(η5-C5H4-E–E–η5-C5H4)V(η7-C7H7) 2·· (E = S), 3·· (E = Se), and 4·· (E = Te) were prepared by a novel path in which the elemental chalcogen atoms serve as suppliers of the hetero-
Autor:
Sima Haddadpour, Mathias Nowotny, Werner Uhl, Christoph Elschenbroich, Andreas Vogelpohl, Stefan Grimme, Madhat Matar
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 635:2027-2033
Treatment of [5]trovacenylethyne, (η7-C7H7)V(η5-C5H4–C≡C–H) (1) with dialkylelement hydrides R2E–H (2: E = Al, R = tBu; 3: E = Ga, R = Et; 4: E = Ga, R = tBu) afforded the corresponding alkynyl-dialkylelement compounds by the release of dih
Publikováno v:
European Journal of Inorganic Chemistry. 2008:3303-3309
Reductive complexation of RuCl3 and OsCl3 in the presence of phosphinine C5H5P and arsenine C5H5As yields the species trans-Cl2(η1-C5H5E)4MII (M = Ru, E = P, As; M = Os, E = P). trans-Cl2(η1-C5H5As)4Ru constitutes the first arsenine complex of a la
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 633:2386-2394
By means of lithiation and subsequent derivatization [5]trovacenyl-diphenylsilanol (2·), di([5]trovacenyl)tetraphenyl-disiloxane (3··), di([5]trovacenyl)tetramethyl-disiloxane (4··) and di([5]trovacenyldimethylsilyl)methane (6··) have been pre
Autor:
and Clemens Pietzonka, Feng Lu, Klaus Harms, Olaf Burghaus, Mathias Nowotny, Christoph Elschenbroich
Publikováno v:
Organometallics. 26:4025-4030
In order to study intermetallic interactions in a tetranuclear complex with tetrahedral disposition of paramagnetic central metal atoms, the organometallic tetraradical [(η7-C7H7)V(η5-C5H4)]4Sn (34•), tetra([5]trovacenyl)tin, was prepared, charac
Autor:
Bernhard Metz, Frank H. Köhler, Basil Kanellakopulos, Rodrigue Lescouëzec, Christoph Elschenbroich, Norbert W. Mitzel, Werner Strauß
Publikováno v:
Chemistry - A European Journal. 13:1191-1200
The reaction of [{(C5Me5)-CrCl2}(2)] with [2.2](1,4)cyclophane gave [(C5Me5)Cr{[2.2](1,4)cyclophane}] (1) and [(C5Me5)Cr{[2.2](1,4)cyclophane}-Cr(C5Me5)] (2), depending on the reaction conditions. X-ray structure analysis showed 2 to be a ministack w