Zobrazeno 1 - 10
of 38
pro vyhledávání: '"Christo S. Sevov"'
Autor:
Heather A. Hintz, Christo S. Sevov
Publikováno v:
Nature Communications, Vol 13, Iss 1, Pp 1-7 (2022)
This work leverages substrate self-assembly at an electrode to promote selective substrate electrooxidation in the presence of oxidatively sensitive catalysts. This strategy is applied to decarboxylative coupling of carboxylic acids with olefins.
Externí odkaz:
https://doaj.org/article/55aa649424424e829d24176601c524e2
Autor:
Koen H. Hendriks, Sophia G. Robinson, Miles N. Braten, Christo S. Sevov, Brett A. Helms, Matthew S. Sigman, Shelley D. Minteer, Melanie S. Sanford
Publikováno v:
ACS Central Science, Vol 4, Iss 2, Pp 189-196 (2018)
Externí odkaz:
https://doaj.org/article/1b14e4b57fe14301a65dca0e0bdd9173
Publikováno v:
ACS Energy Letters. 7:3337-3344
Publikováno v:
ACS Catal
Electroreductive cross-electrophile coupling (eXEC) represents an attractive approach for the direct C-C coupling of two electrophiles but generally suffers from limited scope compared to reactions with chemical reductants. This work demonstrates tha
Autor:
Radoslav Z. Pavlović, Lei Zhiquan, Tyler J. Finnegan, Christopher A. Waudby, Xiuze Wang, Vageesha W. Liyana Gunawardana, Xingrong Zhu, Curt M. Wong, Taylor Hamby, Curtis E. Moore, Nicole Hoefer, David W. McComb, Christo S. Sevov, Jovica D. Badjić
Publikováno v:
Angewandte Chemie International Edition. 61
In this study, we describe a synthetic method for incorporating arenes into closed tubes that we name capsularenes. First, we prepared vase-shaped molecular baskets 4-7. The baskets comprise a benzene base fused to three bicycle[2.2.1]heptane rings t
Publikováno v:
J Am Chem Soc
Simple copper salts serve as catalysts to effect C–X bond-forming reactions in some of the most utilized transformations in synthesis, including the oxidative coupling of aryl boronic acids and amines. However, these Chan–Lam coupling reactions h
Autor:
Curt M. Wong, Christo S. Sevov
Publikováno v:
ACS Energy Letters. :1271-1279
Large-scale integration of renewable energies into the electrical grid will remain limited until high-capacity storage systems are developed to modulate the intermittency of harvestable sources. Th...
Publikováno v:
Science
Cross-electrophile coupling (XEC) reactions of aryl and alkyl electrophiles are appealing but limited to specific substrate classes. Here, we report electroreductive XEC of previously incompatible electrophiles including tertiary alkyl bromides, aryl
Publikováno v:
Journal of the American Chemical Society. 142:5884-5893
Cross-electrophile coupling (XEC) of alkyl and aryl halides promoted by electrochemistry represents an attractive alternative to conventional methods that require stoichiometric quantities of high-energy reductants. Most importantly, electroreduction
Publikováno v:
Journal of the American Chemical Society. 142:3024-3031
The direct and scalable electroreduction of triphenylphosphine oxide (TPPO)-the stoichiometric byproduct of some of the most common synthetic organic reactions-to triphenylphosphine (TPP) remains an unmet challenge that would dramatically reduce the