Zobrazeno 1 - 10
of 17
pro vyhledávání: '"Christina Knispel"'
Publikováno v:
Angewandte Chemie. 124:2277-2280
Publikováno v:
Chemistry - A European Journal. 17:2931-2938
By employing the 2,2'-thiobis(2,4-di-tert-butylphenolate) ligand ((S)L(2-)) a novel oxovanadium(V) complex, (PPh(4))(2)[(S)LV(O)(μ(2)-O)(2)V(O)(S)L] (1), was synthesised that exhibits haloperoxidase activity: on addition of H(2)O(2) a sequence of su
Autor:
Christina Knispel, Reinhard Stösser, Christian Limberg, Stefan Pfirrmann, Christian Herwig, Eckhard Bill, Beatrice Braun
Publikováno v:
Journal of the American Chemical Society. 132:13684-13691
An investigation concerning the stepwise reduction of the β-diketiminato nickel(II) hydride dimer [LNi(μ-H)(2)NiL], 1 (L = [HC(CMeNC(6)H(3)(iPr)(2))(2)](-)), has been carried out. While the reaction with one equivalent of potassium graphite, KC(8),
Publikováno v:
Organometallics. 29:1670-1674
The reaction of rhenocene hydride with bismuth alkoxides leads to complexes containing Re−Bi metal bonds with concomitant formation of the corresponding alcohols. Hence, compounds of the type [Cp2R...
Publikováno v:
Organometallics. 28:646-651
First, the reactivity of molybdocene dihydride toward bismuth siloxides was studied. Depending on the stoichiometry, compounds of the type [Cp2Mo{Bi(OR)2}2] (R = SiMe2tBu, 1, R = SiPh3, 3) or [Cp2Mo(μ-BiOR)2MoCp2] (R = SiMe2tBu, 2t, R = SiPh3, 4t) w
Publikováno v:
Zeitschrift für anorganische und allgemeine Chemie. 633:2278-2284
With the background of the interesting reactivities and novel compounds revealed by investigations concerning the system [RCp2MoH2] and Bi(OtBu)3, analogous reactions of [MeCp2MoH2] with Sb(OtBu)3, SbCl3, SnCl2 and SnCl4 were examined. After treatmen
Autor:
Christian Limberg, Christina Knispel
Publikováno v:
Organometallics. 30:3701-3703
The reaction of [LBiNMe2], I (L = [1,8-C10H6(NSiMe3)2]2–), with [MeCp2Mo═O] results in a coordination of the Mo═O group at the Bi center, which in turn triggers C–H activation at the methylcyclopentadienyl ligand through complex-induced proxi
Publikováno v:
Angewandte Chemie (International ed. in English). 51(9)
Publikováno v:
Chemical communications (Cambridge, England). 47(38)
Reaction of [Cp(2)MoH(2)] with bismuth allyloxide, [Bi{OCH(CH(3))CH==CH(2)}(3)], gave rise to an extended octanuclear complex wherein two cyclic Mo(2)Bi(2) units composed of four Mo-Bi bonds are linked by a Bi-Bi bond. The fact that the construction
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 17(43)
On the basis that thiacalix[4]arene (H(4)T4A) complex (PPh(4) )(2) [H(2)T4A(VO(2))](2) (Ia) was found to be an adequate functional model for surface species occurring on vanadium oxide based catalysts and itself catalyses the oxidative dehydrogenatio