Zobrazeno 1 - 10
of 18
pro vyhledávání: '"Christiana Xin Zhang"'
Autor:
Andreas D. Zuberbühler, Benedikt Galliker, Kenneth D. Karlin, Arnold L. Rheingold, Christiana Xin Zhang, Susan Kaderli
Publikováno v:
Inorganica Chimica Acta. 389:138-150
Copper-dioxygen interactions are of intrinsic importance in a wide range of biological and industrial processes. Here, we present detailed kinetic/thermodynamic studies on the O(2)-binding and arene hydroxylation reactions of a series of xylyl-bridge
Publikováno v:
Journal of the American Chemical Society. 127:5469-5483
A series of copper-dioxygen adducts [{Cu(II)(MePY2)(R)}(2)(O(2))](B(C(6)F(5))(4))(2) (1(R)()), systematically varying in their electronic properties via ligand pyridyl donor substituents (R = H, MeO, and Me(2)N), oxidize a variety of substrates with
Autor:
Edward I. Solomon, Christiana Xin Zhang, Mark J. Henson, Hong-Chang Liang, Kenneth D. Karlin, Michael A. Vance
Publikováno v:
Journal of the American Chemical Society. 125:5186-5192
The effect of endogenous donor strength on Cu(2)O(2) bonds was studied by electronically perturbing [[(R-TMPA)Cu(II)]](2)(O(2))](2+) and [[(R-MePY2)Cu](2)(O(2))](2+) (R = H, MeO, Me(2)N), which form the end-on mu-1,2 bound peroxide and an equilibrium
Autor:
Christiana Xin Zhang, Andreas D. Zuberbühler, Susan Kaderli, † Eun-il Kim, Kenneth D. Karlin, Yorck-Michael Neuhold, Miguel Costas
Publikováno v:
Inorganic Chemistry. 42:1807-1824
The kinetic and thermodynamic behavior of O2-binding to Cu(I) complexes can provide fundamental understanding of copper(I)/dioxygen chemistry, which is of interest in chemical and biological systems. Here we report stopped-flow kinetic investigations
Autor:
Edward I. Solomon, Kenneth D. Karlin,† and, Christiana Xin Zhang, Elna Pidcock, Honorio V. Obias
Publikováno v:
Journal of the American Chemical Society. 120:7841-7847
The kinetics of the reaction, via an oxygen-bound intermediate, of [CuI2(NO2-XYL)][ClO4]2·CH3CN to [Cu2(NO2-XYL-O-)(OH)]2+, where the bridging arene is hydroxylated, have been examined with use of resonance Raman spectroscopy. A resonance Raman peak
Autor:
Andreas D. Zuberbühler, Lanying Q. Hatcher, Mark J. Henson, Roger D. Sommer, Edward I. Solomon, Susan Kaderli, Hong-Chang Liang, Kenneth D. Karlin, Michael A. Vance, David Lahti, Arnold L. Rheingold, Christiana Xin Zhang
Publikováno v:
Inorganic Chemistry. 43:4115-4117
A new tridentate ligand, PYAN, is employed to investigate solvent influences for dioxygen reactivity with [Cu(PYAN)(MeCN)]B(C(6)F(5))(4) (1). Stopped-flow kinetic studies confirm that the adducts [[u(II)(PYAN)]2)(O(2))][B(C(6)F(5))(4)](2) (2(Peroxo))
Publikováno v:
Chembiochem : a European journal of chemical biology. 10(1)
The activity of the anticancer drug cisplatin is a consequence of its ability to bind DNA. Platinum adducts bend and unwind the DNA duplex, creating recognition sites for nuclear proteins. Following DNA damage recognition, the lesions will either be
Publikováno v:
Current opinion in chemical biology. 7(4)
The many activities of metal ions in biology have stimulated the development of metal-based therapeutics. Cisplatin, as one of the leading metal-based drugs, is widely used in treatment of cancer, being especially effective against genitourinary tumo
Publikováno v:
ChemInform. 34
Publikováno v:
Advances in Catalytic Activation of Dioxygen by Metal Complexes ISBN: 9781402010743
Copper-dioxygen interactions are essential from both industrial and biological perspectives. This review will focus on recent advances in copper-dioxygen complexes with regard to their relevance to bioinorganic chemistry. New, room-temperature stable
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::4ce18c39d4572b56d64df0bc92a1e972
https://doi.org/10.1007/0-306-47816-1_2
https://doi.org/10.1007/0-306-47816-1_2