A homoleptic tris(diphosphacyclobutadiene) tripledecker sandwich complex

Autor: Christian Rödl, Gabriele Hierlmeier, Robert Wolf

The synthesis and characterisation of [Co2(η4 P2C2tBu2)2(µ:η4:η4-P2C2tBu2)] (1) is described, featuring two cobalt atoms and three diphosphacyclobutadiene ligands. This compound is the first triple-decker sandwich complex which exclusively contai

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7a9c667412917e0b93e5f54a2b74e979
https://doi.org/10.26434/chemrxiv-2022-qkq2w

1,3‐Diphosphacyclobutene Cobalt Complexes

Autor: Christian Rödl, Robert Wolf, Kai Schwedtmann, Jan J. Weigand

Publikováno v: Chemistry – A European Journal. 25:6180-6188

The synthesis and characterization of rare 1,3-diphosphacyclobutene transition-metal complexes is described. Reactions of the cobalt-hydride complex [Co(P(2)C(2)tBu(2))(2)H] (G) with nBuLi, tBuLi, or PhLi afforded [Li(solv)(x){Co(eta(3)-P(2)C(2)tBu(2

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c6912e1637173e5a4efacb808f5699f5
https://doi.org/10.1002/chem.201900170

Synthesis of a Cyclic Co2Sn2 Cluster Using a Co– Synthon

Autor: Christian Rödl, Madison L. McCrea-Hendrick, Theresa Block, Christian M. Hoidn, Rainer Pöttgen, Philip P. Power, Robert Wolf, Andreas W. Ehlers

Publikováno v: Journal of the American Chemical Society, 140(41), 13195-13199. American Chemical Society
Journal of the American Chemical Society
Journal of the American Chemical Society, vol 140, iss 41

[Ar′SnCo]2 (1, Ar′ = C6H3-2,6{C6H3-2,6-iPr2}2), a rare metal–metal bonded cobalt–tin cluster with low-coordinate tin atoms, was prepared by the reaction of [K(thf)0.2][Co(1,5-cod)2] (cod = 1,5-cyclooctadiene) with [Ar′Sn(μ-Cl)]2. This reac

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https://doi.org/10.1021/jacs.8b08517

Oxidative P-P-Bindungsaddition an Cobalt(−I): Bildung eines Low-spin-Cobalt(III)-Phosphanidokomplexes

Autor: Christian Rödl, Evamarie Hey-Hawkins, Serhiy Demeshko, Robert Wolf, Peter Coburger

Publikováno v: Angewandte Chemie. 129:16087-16091

Die oxidative P-P-Bindungsaddition eines ortho-Carboran-substituierten 1,2-Diphosphetans an Cobalt(−I) in [K(thf)0.2][Co(η4-cod)2)] (cod=1,5-Cycloctadien) ermoglichte die Darstellung des ersten homoleptischen Cobalt(III)-Phosphanidokomplexes [K(th

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::a29c7acb882b00c2b64e9327db751bd8
https://doi.org/10.1002/ange.201709140

Synthesis, electronic structure and redox properties of the diruthenium sandwich complexes [Cp*Ru(μ-C

Autor: Dirk, Herrmann, Christian, Rödl, Bas, de Bruin, František, Hartl, Robert, Wolf

Publikováno v: Dalton transactions (Cambridge, England : 2003). 47(32)

The dinuclear ruthenium complex [Cp*Ru(μ-C10H8)RuCp*] (1; Cp* = η5-C5Me5) was prepared by reduction of the cationic precursor [Cp*Ru(η6-C10H8)]PF6 with KC8. Diamagnetic 1 has a symmetric molecular structure with an anti-facial configuration of the

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::a18df0a0d80d7b083d102dd65ce736c4
https://pubmed.ncbi.nlm.nih.gov/30027943