Zobrazeno 1 - 10
of 16
pro vyhledávání: '"Christian P. Lenges"'
Publikováno v:
ACS Sustainable Chemistry & Engineering. 10:10718-10732
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::4d87aba6e831028d7acf79c039e5452a
https://doi.org/10.1021/acssuschemeng.2c03466
https://doi.org/10.1021/acssuschemeng.2c03466
Publikováno v:
Journal of the American Chemical Society. 129:2082-2093
Rhodium (I) bis-olefin complexes Cp*Rh(VTMS)(2) and CpRh(VTMS)(2) (Cp* = C(5)Me(5), Cp = C(5)Me(4)CF(3), VTMS = vinyl trimethylsilane) were found to catalyze the addition of aromatic aldehydes to olefins to form ketones. Use of the more electron-defi
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::8f3523effed1ae1bbcd3175cc8d00f00
https://doi.org/10.1021/ja066509x
https://doi.org/10.1021/ja066509x
Publikováno v:
Angewandte Chemie International Edition. 39:1676-1679
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::e2e0af584c71e1482f6f5222a272418d
https://doi.org/10.1002/(sici)1521-3773(20000502)39:9<1676::aid-anie1676>3.0.co
https://doi.org/10.1002/(sici)1521-3773(20000502)39:9<1676::aid-anie1676>3.0.co
Publikováno v:
Angewandte Chemie. 112:1742-1745
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::ceb3b396d7c0fe67983f3a1d31041376
https://doi.org/10.1002/(sici)1521-3757(20000502)112:9<1742::aid-ange1742>3.0.co
https://doi.org/10.1002/(sici)1521-3757(20000502)112:9<1742::aid-ange1742>3.0.co
Publikováno v:
Organometallics. 19:1247-1254
The bis(olefin) complex [C5Me5Co(C2H3SiMe3)2] (6) reacts with pyridine at 22 °C to give the pyridine olefin complex [C5Me5Co(C2H3SiMe3)(C5H5N)] (7). The addition of excess pyridine does not result in the formation of a bis(pyridine) adduct. Thermoly
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::376bdba031cf101fd3aa335914961014
https://doi.org/10.1021/om990860s
https://doi.org/10.1021/om990860s
Autor:
Maurice Brookhart, Christian P. Lenges
Publikováno v:
Angewandte Chemie. 111:3746-3750
Ein Gemisch isomerer Aldehyde wird bei einer von [C5Me5Rh(olefin)2]-Komplexen katalysierten Isomerisierung von Alkylaldehyden gebildet. Dies ist eine indirekte Methode zur Beeinflussung des n:iso-Verhaltnisses von Aldehyden, die bei Hydroformylierung
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::0fe71b90e738bb24b28657ce44ae709f
https://doi.org/10.1002/(sici)1521-3757(19991203)111:23<3746::aid-ange3746>3.0.co
https://doi.org/10.1002/(sici)1521-3757(19991203)111:23<3746::aid-ange3746>3.0.co
Autor:
Maurice Brookhart, Christian P. Lenges
Publikováno v:
Angewandte Chemie International Edition. 38:3533-3537
A mixture of isomeric aldehydes is formed in a catalytic isomerization of alkyl aldehydes with [C(5)Me(5)Rh(olefin)(2)] complexes. This process offers an indirect method for altering the n:iso ratio of aldehydes formed in hydroformylation reactions.
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::f7393d16e72692c4d6ea49cb969f598e
https://doi.org/10.1002/(sici)1521-3773(19991203)38:23<3533::aid-anie3533>3.0.co
https://doi.org/10.1002/(sici)1521-3773(19991203)38:23<3533::aid-anie3533>3.0.co
Autor:
Maurice Brookhart, Christian P. Lenges
Publikováno v:
Journal of the American Chemical Society. 121:6616-6623
The rhodium bis-olefin complex [C5Me5Rh(C2H3SiMe3)2], 1, has been shown to be a catalyst for the selective addition of olefins to the ortho position of aromatic ketones. The addition of vinyltrimethylsilane to benzophenone was studied by NMR spectros
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::88ae783ebefafe8861cbbb56203ee96e
https://doi.org/10.1021/ja990702s
https://doi.org/10.1021/ja990702s
Publikováno v:
Journal of the American Chemical Society. 121:4385-4396
A series of [C5Me5Rh(CH2CHR)2] complexes (1a−e) have been prepared in which the olefin bears a bulky silyl substituent, R = (a) SiMe3, (b) SiMe2OEt, (c) Si(OiPr)3, (d) SiMe(OSiMe3)2, (e) SiPh2OiPr. The solid-state structure of 1c has been determine
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::5ba984767285f993ede64eac7d5a4b71
https://doi.org/10.1021/ja984409o
https://doi.org/10.1021/ja984409o
Publikováno v:
Angewandte Chemie. 111:535-538
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::41b71dee35fd010ba695c6dbac256461
https://doi.org/10.1002/(sici)1521-3757(19990215)111:4<535::aid-ange535>3.0.co
https://doi.org/10.1002/(sici)1521-3757(19990215)111:4<535::aid-ange535>3.0.co