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pro vyhledávání: '"Christian Mehnert"'
Publikováno v:
Journal of Organometallic Chemistry. 491:47-55
High yield syntheses of neutral and cationic aminocarbyne complexes of chromium-bearing isocyanide ligands are reported. Neutral complexes of the type Br(CO)2(RNC)2CrCNiPr2(R = Et(3a); R =tBu (3b)) are obtained from Br(CO)2(pic)2CrCNiPr2 (2) (p
Publikováno v:
Journal of Organometallic Chemistry. 461:99-109
Efficient methods are described for the synthesis of half-sandwich chromium aminocarbyne complexes starting from trans -X(CO) 4 CrCN i Pr 2 ( 1a: X Cl; 1b: X Br). Complexes 1a and 1b are obtained from Cr(CO) 6 in two steps. The first step