Synthesis of a Cyclic Co2Sn2 Cluster Using a Co– Synthon

Autor: Christian Rödl, Madison L. McCrea-Hendrick, Theresa Block, Christian M. Hoidn, Rainer Pöttgen, Philip P. Power, Robert Wolf, Andreas W. Ehlers

Publikováno v: Journal of the American Chemical Society, 140(41), 13195-13199. American Chemical Society
Journal of the American Chemical Society
Journal of the American Chemical Society, vol 140, iss 41

[Ar′SnCo]2 (1, Ar′ = C6H3-2,6{C6H3-2,6-iPr2}2), a rare metal–metal bonded cobalt–tin cluster with low-coordinate tin atoms, was prepared by the reaction of [K(thf)0.2][Co(1,5-cod)2] (cod = 1,5-cyclooctadiene) with [Ar′Sn(μ-Cl)]2. This reac

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5de004adea70eee7af2126bfad8c5bec
https://doi.org/10.1021/jacs.8b08517

Reaction of a 2,4,6-triphenylphosphinine ferrate anion with electrophiles: a new route to phosphacyclohexadienyl complexes

Autor: Christian M. Hoidn, Robert Wolf

Publikováno v: Dalton Transactions. 45:8875-8884

A novel, versatile route to phosphorus- and carbon-substituted η(5)-phosphacyclohexadienyl complexes was developed. Reaction of the anionic 2,4,6-triphenylphosphinine iron complex [K([18]crown-6)(thf)2][Cp*Fe(PC5Ph3H2)] (1) with selected main group

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::22ae5cd7ebf1fb7f0ea14c25117e3d92
https://doi.org/10.1039/c6dt00336b

Halide‐Substituted Phosphacyclohexadienyl Iron Complexes: Covalent Structures vs. Ion Pairs

Autor: Christian M. Hoidn, Ilya G. Shenderovich, Christoph Ziegler, Julia Leitl, Robert Wolf

Publikováno v: European Journal of Inorganic Chemistry. 2019:1434-1434

Invited for the cover of this issue is the group of Robert Wolf from the University of Regensburg, Germany. The cover image shows the structure of the first transition metal complexes bearing pi-coordinated lambda(3)-halophosphacyclohexadienyl ligand

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7a56ba13dd71c74d6801773c7f73a29f
https://doi.org/10.1002/ejic.201900234