Zobrazeno 1 - 10
of 10
pro vyhledávání: '"Christian M. Frech Nabold"'
Publikováno v:
Chemistry - A European Journal. 16:11072-11081
[Pd(Cl)(2){P(NC(5)H(10))(C(6)H(11))(2)}(2)] (1) has been prepared in quantitative yield by reacting commercially available [Pd(cod)(Cl)(2)] (cod=cyclooctadiene) with readily prepared 1-(dicyclohexylphosphanyl)piperidine in toluene under N(2) within a
Publikováno v:
Advanced Synthesis & Catalysis. 351:891-902
Sequential addition of 1,1',1"-phosphine-triyltripiperidine and 1,3-diaminobenzene or resorcinol to toluene solutions of (cyclooctadiene)palladium dichloride [Pd(cod)(Cl) 2 ] under nitrogen in "one pot" almost quantitatively yielded the aminophosphin
Publikováno v:
Angewandte Chemie International Edition. 46:6514-6517
Feeling the pinch: Aryl bromides can be coupled with phenylboronic acid quantitatively within a few minutes by using pincer‐type catalysts bearing aminophosphine substituents. [Pd(Cl)2P(NR2)3] has been used as a template for the pincer core directl
Publikováno v:
ChemCatChem. 2:1387-1389
Find the answer within: Transformations within molecular single crystals of organometallic compounds are very rare and usually involve (reversible) loss of solvent molecules or ligands. A great stride forward in the field of such transformations was
Dichloro-bis(aminophosphine) complexes are stable depot forms of palladium nanoparticles and have proved to be excellent Suzuki-Miyaura catalysts. Simple modifications of the ligand (and/or the addition of water to the reaction mixture) have allowed
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::1986fa7c2f55521dd429c8fafba96055
https://hdl.handle.net/11475/10468
https://hdl.handle.net/11475/10468
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 16(5)
Pincer-type palladium complexes are among the most active Heck catalysts. Due to their exceptionally high thermal stability and the fact that they contain Pd(II) centers, controversial Pd(II)/Pd(IV) cycles have been often proposed as potential cataly
Publikováno v:
CHIMIA, Vol 63, Iss 1-2 (2009)
The aminophosphine-based pincer complexes [C6H3-2,6-{NHP(piperidinyl)2}2Pd(Cl)] (2) and [C6H3-2,6-{OP(piperidinyl)2}2Pd(Cl)] (3) are readily prepared from cheap starting materials by sequential addition of 1,1?,1?-phosphinetriyltripiperidine and 1,3-
A simple and reliable reaction protocol for the clean, fast, and high-yielding synthesis of various N-arylated amines derived from reactions of aryl halides with various (also sterically hindered) amines under transition metal-free reaction condition
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a02cd6e1349be363c2a0ff143dc13b7a
https://hdl.handle.net/11475/10483
https://hdl.handle.net/11475/10483
The aminophosphine-based pincer complexes [C6H3-2,6-(XP(piperidinyl)2)2Pd(Cl)] (X=NH 1; X=O 2) are readily prepared from cheap starting materials by sequential addition of 1,1',1''-phosphinetriyltripiperidine and 1,3-diaminobenzene or resorcinol to s
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::797dd21c21252e63a5eb7b6fab121304
https://hdl.handle.net/11475/10510
https://hdl.handle.net/11475/10510
Publikováno v:
Acta Crystallographica Section E Structure Reports Online. 63:m3086-m3086
The title compound, [PdBr(C26H43N4O2P2)], a so-called palladium pincer complex, is a very efficient catalyst for the Suzuki cross-coupling reaction. The Pd atom exhibits a distorted square-planar coordination, typical for PdII complexes.