Zobrazeno 1 - 10
of 22
pro vyhledávání: '"Christian Graßl"'
Autor:
Mehdi Elsayed Moussa, Susanne Bauer, Christian Graßl, Christoph Riesinger, Gábor Balázs, Manfred Scheer
Publikováno v:
Molecules, Vol 29, Iss 9, p 2025 (2024)
Phosphorus- and arsenic-containing cobalt clusters are an interesting class of compounds that continue to provide new structures with captivating bonding patterns. Although the first members of this family were reported 45 years ago, the number of su
Externí odkaz:
https://doaj.org/article/caf29e77bfbd4fb7bc2c61ae7a24489b
Publikováno v:
Chemistry – A European Journal. 27:18129-18134
The reactivity of white phosphorus and yellow arsenic towards two different nickel nacnac complexes is investigated. The nickel complexes [(L 1 Ni) 2 tol] ( 1 , L 1 = [{N(C 6 H 3 i Pr 2 -2,6)C(Me)} 2 CH] - ) and [K 2 ][(L 1 Ni) 2 ( μ , η 1:1 -N 2 )
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b9489ad35b684e9e5ba7291e66ed2ac8
https://doi.org/10.1002/chem.202103372
https://doi.org/10.1002/chem.202103372
Publikováno v:
Angewandte Chemie. 132:7220-7227
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::807d4a06437b6ab9cca60cca8d850f16
https://doi.org/10.1002/ange.201916622
https://doi.org/10.1002/ange.201916622
Publikováno v:
Angewandte Chemie (International Ed. in English)
The redox chemistry of [(Cp′′′Co)2(μ,η2:η2‐E2)2] (E=P (1), As (2); Cp′′′=1,2,4‐tri(tert‐butyl)cyclopentadienyl) was investigated. Both compounds can be oxidized and reduced twice. That way, the monocations [(Cp′′′Co)2(μ,η
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::7aee2276566e1c19838a60c76e792f68
http://europepmc.org/articles/PMC7216884
http://europepmc.org/articles/PMC7216884
Publikováno v:
Chemical Communications. 56:13209-13212
Different substituents at the β-diiminato ligand in low-valent [LFe(tol)] (L = β-diiminato) complexes fundamentally change their reactivity towards yellow arsenic. By using dmp (2,6-dimethylphenyl) as flanking groups, the tetranuclear complexes [(L
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::0466b7638ce110d77a33ec0a1d22f03f
https://doi.org/10.1039/d0cc05173j
https://doi.org/10.1039/d0cc05173j
Publikováno v:
Chemistry (Weinheim an der Bergstrasse, Germany). 27(72)
The reactivity of white phosphorus and yellow arsenic towards two different nickel nacnac complexes is investigated. The nickel complexes [(L
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::6b2cd2f0a40c8d6d15bcc65cb6b96c93
https://pubmed.ncbi.nlm.nih.gov/34730858
https://pubmed.ncbi.nlm.nih.gov/34730858
Publikováno v:
Chemical communications (Cambridge, England). 56(86)
Different substituents at the β-diiminato ligand in low-valent [LFe(tol)] (L = β-diiminato) complexes fundamentally change their reactivity towards yellow arsenic. By using dmp (2,6-dimethylphenyl) as flanking groups, the tetranuclear complexes [(L
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=pmid________::53b07be5e9d13ca56d682737b2b31ec7
https://pubmed.ncbi.nlm.nih.gov/33026371
https://pubmed.ncbi.nlm.nih.gov/33026371
Autor:
Martin Keilwerth, Karsten Meyer, Christian Graßl, Manfred Scheer, Fabian Spitzer, Gábor Balázs
Publikováno v:
Angewandte Chemie. 130:8896-8900
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::60eb54998c30a86a3c790e11b865dfe0
https://doi.org/10.1002/ange.201802888
https://doi.org/10.1002/ange.201802888
Autor:
Gábor Balázs, Christian Graßl, Manfred Scheer, Fabian Spitzer, Martin Keilwerth, Karsten Meyer
Publikováno v:
Angewandte Chemie (International Ed. in English)
In a systematic study of the activation of As-4, three [LCo(tol)] (L=beta-diiminato) complexes have revealed different steric and electronic influences. 2,6-Diisopropylphenyl (Dipp) and 2,6-dimethylphenyl (dmp) flanking groups were used, one of the l
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::4a97e6fae346dc79b696feb3639d4e55
http://europepmc.org/articles/PMC6099418
http://europepmc.org/articles/PMC6099418
Autor:
Karsten Meyer, Fabian Spitzer, Eric Mädl, Manfred Scheer, Martin Keilwerth, Christian Graßl, Eva M. Zolnhofer, Gábor Balázs
Publikováno v:
Chemistry (Weinheim an Der Bergstrasse, Germany)
A comparison of P-4 activations mediated by lowvalent beta-diketiminato (L) cobalt complexes is presented. The formal Co-0 source [K-2((LCo)-Co-3)(2)(mu(2):eta(1), eta(1)-N-2)] (1) reacts with P-4 to form a mixture of the monoanionic complexes [K(thf
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e0e2f8bc289cd11790a61066fd5f4090
https://doi.org/10.1002/chem.201605451
https://doi.org/10.1002/chem.201605451