Zobrazeno 1 - 10
of 20
pro vyhledávání: '"Christian G. Hartung"'
Autor:
Harald Trauthwein, Christian G. Hartung, Oliver R. Thiel, Martin Eichberger, Jayasree Seayad, Claudia Breindl, Matthias Beller, Annegret Tillack
Publikováno v:
Synlett. :1579-1594
Recent developments in the area of transition metal-catalyzed amination of olefins and alkynes are reviewed. Special emphasis is given to rhodium-catalyzed oxidative aminations of aromatic olefins.
Publikováno v:
The Journal of Organic Chemistry. 66:6339-6343
The first rhodium-catalyzed intermolecular hydroamination of alkynes is presented. Terminal alkynes react efficiently with anilines in the presence of cationic rhodium(I) catalysts under very mild reaction conditions (e.g., base and acid free at room
Autor:
Annegret Tillack, Harald Trauthwein, Christian G. Hartung, Martin Eichberger, Stephan Pitter, Achim Jansen, Matthias Beller
Publikováno v:
Monatshefte fuer Chemie/Chemical Monthly. 131:1327-1334
Publikováno v:
Chemistry - A European Journal. 6:2513-2522
A new catalytic amination of aromatic olefins with anilines is presented. In a domino reaction, substituted quinoline derivatives are obtained in the presence of cationic rhodium complexes, such as [Rh(cod)2]BF4, and PPh3. Ethylbenzene is formed as a
Publikováno v:
Tetrahedron. 56:5157-5162
An efficient synthesis of pharmaceutically interesting amphetamines by a base-catalyzed domino-isomerization–hydroamination reaction is presented. Starting from allylbenzene and various primary or secondary amines, the basic structural pattern of a
Publikováno v:
Angewandte Chemie. 114:2646-2648
Publikováno v:
ChemInform. 30
Publikováno v:
ChemInform. 33
The first rhodium-catalyzed intermolecular hydroamination of alkynes is presented. Terminal alkynes react efficiently with anilines in the presence of cationic rhodium(I) catalysts under very mild reaction conditions (e.g., base and acid free at room
Publikováno v:
ChemInform. 33
Publikováno v:
Organic Letters. 1:709-711
[reaction: see text] The influence of palladium catalysts and reaction conditions on the selectivity of Heck reactions of aryl bromides with cyclohexene and cyclopentene has been investigated. It is shown that the addition of DMSO as a cosolvent lead