Sustainable Polythioesters via Thio(no)lactones: Monomer Synthesis, Ring‐Opening Polymerization, End‐of‐Life Considerations, and Industrial Perspectives

Autor: An Sofie Narmon, Christian A. M. R. van Slagmaat, Stefaan M. A. De Wildeman, Michiel Dusselier

Publikováno v: ChemSusChem. 16

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_________::9536dd08e98d705fd728d54def58fc3e
https://doi.org/10.1002/cssc.202202276

Hydrogenation of Cyclic 1,3-Diones to Their 1,3-Diols Using Heterogeneous Catalysts: Toward a Facile, Robust, Scalable, and Potentially Bio-Based Route

Autor: Stefaan M. A. De Wildeman, Christian A. M. R. van Slagmaat, Paul L. Alsters, Gerard K. M. Verzijl, Peter J. L. M. Quaedflieg

Publikováno v: ACS Omega
ACS Omega, Vol 6, Iss 6, Pp 4313-4328 (2021)
Acs omega, 6(6), 4313-4328. American Chemical Society

Cyclopentane-1,3-diol (4b) has gained renewed attention as a potential building block for polymers and fuels because its synthesis from hemicellulose-derived 4-hydroxycyclopent-2-enone (3) was recently disclosed. However, cyclopentane1,3-dione (4), w

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::c193640784c758a9feed7c292fc67672
http://europepmc.org/articles/PMC7893635

Organocatalyzed ring opening polymerization of regio-isomeric lactones

Autor: Jules Stouten, Stefaan M. A. De Wildeman, Marie A. F. Delgove, Christian A. M. R. van Slagmaat, Jurrie Noordijk, Katrien V. Bernaerts, Aleksandra Wroblewska

Publikováno v: Polymer Chemistry, 11(21), 3573-3584. Royal Society of Chemistry

Organocatalysts are increasingly gaining attention for the ring opening polymerization (ROP) of lactones due to numerous advantages. In this work, the goal is to expand the scope of catalysts for the ROP of alkyl substituted caprolactones: a mixture

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::b38c48015dc9950a175fa2a613130678
https://cris.maastrichtuniversity.nl/en/publications/9fe64c3e-315b-4f33-a550-647e98bc15e0

Chemoselective formation of cyclo-aliphatic and cyclo-olefinic 1,3-diols

Autor: Christian A M R, van Slagmaat, Teresa, Faber, Khi Chhay, Chou, Alfonso J, Schwalb Freire, Darya, Hadavi, Peiliang, Han, Peter J L M, Quaedflieg, Gerard K M, Verzijl, Paul L, Alsters, Stefaan M A, De Wildeman

Publikováno v: Dalton transactions (Cambridge, England : 2003). 50(29)

The hydrogenative conversions of the biobased platform molecules 4-hydroxycyclopent-2-enone and cyclopentane-1,3-dione to their corresponding 1,3-diols are established using a pre-activated Knölker-type iron catalyst. The catalyst exhibits a high se

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=pmid________::ede86c22896d984a10d24e49b70a852f
https://pubmed.ncbi.nlm.nih.gov/34240727

A Comparative Study of Structurally Related Homogeneous Ruthenium and Iron Catalysts for the Hydrogenation of Levulinic Acid to -Valerolactone

Autor: Christian A. M. R. van Slagmaat, Stefaan M. A. De Wildeman

Publikováno v: European Journal of Inorganic Chemistry, 694-702. Wiley-VCH Verlag
ISSUE=6;STARTPAGE=694;ENDPAGE=702;ISSN=1434-1948;TITLE=European Journal of Inorganic Chemistry

The conversion of levulinic acid to -valerolactone was investigated by employing the homogeneous Shvo catalyst (Ru-1) and iron Knolker-type catalysts, in order to evaluate the possibility to replace ruthenium with cheap, earth-abundant iron for th

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::e1ddb12a1fc3527abd6846084e2ddd5c
https://cris.maastrichtuniversity.nl/en/publications/bddcca11-6a9e-41e2-be38-337d602791c5