Zobrazeno 1 - 10
of 22
pro vyhledávání: '"Christian Schulte to Brinke"'
Hydrogen Activation by an Iridium(III) Complex Bearing a Bidentate Protic NH,NR-NHC∧Phosphine Ligand
Publikováno v:
Organometallics. 34:5454-5460
Benzimidazole 2 bearing an N1-(biscyclohexylphosphine)ethyl tether cleaves [IrCp*Cl2]2 to yield the mononuclear phosphine complex [3]. Heating of [3] yields via a formal C/N tautomerization complex [4]Cl with a protic NHC. Complex [4]Cl can be N3-dep
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::6bcbc0fd25b423bea90722192eba10ed
https://doi.org/10.1021/acs.organomet.5b00799
https://doi.org/10.1021/acs.organomet.5b00799
Publikováno v:
European Journal of Inorganic Chemistry. 2015:3227-3231
A series of trinuclear heterobimetallic AuI/M2 (M = RhIII, IrIII, RuII) complexes were prepared by the stepwise and selective metalation of a rigid cyclic tetraimidazolium salt. Reaction of the tetraimidazolium salt with exactly 1 equivalent of silve
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::0c967d6f2e05a8a0b4cc866e0a91787f
https://doi.org/10.1002/ejic.201500519
https://doi.org/10.1002/ejic.201500519
Autor:
Alexander Hepp, F. Ekkehardt Hahn, Christian Schulte to Brinke, Hannah Koppetz, Sergei Krupski
Publikováno v:
Organometallics. 34:2624-2631
The monoalkylated or monoarylated o-phenylenediamines 1a–d (1a, R = t-Bu; 1b, R = adamantyl; 1c, R = phenyl; 1d, R = mesityl) react via transamination with Ge[N(SiMe3)2]2 or Sn[N(SiMe3)2]2 to give the protic benzimidazolin-2-germylenes 2a–d or th
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::693d181f7cf34ca86a10c961dfc82dc6
https://doi.org/10.1021/om5012616
https://doi.org/10.1021/om5012616
Publikováno v:
Zeitschrift für Naturforschung B. 69:1248-1252
The 5,5′-bibenzimidazolium dibromide salts 2 and 3 have been prepared by fourfold N-alkylation of 5,5′-bibenzimidazole (2: R=Pr; 3: R=Bu). The diazolium salts were treated with silver oxide, and the in situ-formed silver complexes were subsequent
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::3f6ddcc0060191705f442075a25f53ad
https://doi.org/10.5560/znb.2014-4194
https://doi.org/10.5560/znb.2014-4194
Publikováno v:
Organometallics. 33:4471-4478
Reaction of 2 equiv of 2-azidoethyl isocyanide and the tetraphosphine platinum(II) complexes [1a–c](X)2 (a, PR3 = PMe3; b, PR3 = PMe2Ph; c, PR3 = PMePh2) yielded via phosphine substitution and template-controlled cyclization of the isocyanide ligan
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::950e808afd4afeef965ebc594d446792
https://doi.org/10.1021/om5006947
https://doi.org/10.1021/om5006947
Autor:
F. Ekkehardt Hahn, Mareike C. Jahnke, Dirk Brackemeyer, Alexandre Hervé, Christian Schulte to Brinke
Publikováno v:
Journal of the American Chemical Society. 136:7841-7844
Purine nucleobases are excellent ligands for metal ions, forming normally coordinative Werner-type bonds by utilizing the N donor atoms of the nucleobase skeleton. Here we show that purines such as 8-chlorocaffeine and 8-bromo-9-methyladenine react w
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::b2b88cc030f11e717422e1cf4815a88c
https://doi.org/10.1021/ja5030904
https://doi.org/10.1021/ja5030904
Benzodicarbene-bridged dinuclear complexes as building blocks for metalosupramolecular architectures
Publikováno v:
Journal of Organometallic Chemistry. 751:620-627
Dinuclear benzodicarbene-bridged iridium(III) and rhodium(III) complexes [Cp*(Cl)2M(benzodicarbene)M(Cl)2Cp*] [3]–[5] have been synthesized from N,N′,N″,N″-tetraalkylbenzobisimidazolium salts and [MCp*(Cl)2]2 via the Ag2O method. Molecular st
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::5ec7351af06363f0e4146611a291d9be
https://doi.org/10.1016/j.jorganchem.2013.08.001
https://doi.org/10.1016/j.jorganchem.2013.08.001
Publikováno v:
Organometallics. 32:6174-6177
The bisimidazolium salt H2-1(PF6)2 featuring a bridging 1,4-phenylene group reacts with 0.5 equiv of [PdCl(allyl)]2 in the presence of Cs2CO3 to give the dinuclear complex [2](PF6)2, whereas the reaction of the same bisimidazolium salt with 0.5 equiv
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::73163f5b210175777c4ea782de971d99
https://doi.org/10.1021/om400921c
https://doi.org/10.1021/om400921c
Publikováno v:
Zeitschrift für Naturforschung B. 68:551-556
As a siderophore analog, the tripodal tris(benzene-o-dithiol)-functionalized ligand H6-5, has been synthesized in four steps including the reaction of 1,3,5-(triaminomethyl)-2,4,6-triethylbenzene and 2,3-bis(isopropylmercapto)benzoyl chloride followe
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::0c15aab5ef6afdfe23d1c25de5648f2a
https://doi.org/10.5560/znb.2013-3069
https://doi.org/10.5560/znb.2013-3069
Autor:
Christian Schulte to Brinke, Jutta Kösters, Tania Pape, Kai-Oliver Feldmann, A. Carolin Dumke, F. Ekkehardt Hahn
Publikováno v:
Organometallics. 32:289-299
Reaction of 2-azidoethyl isocyanide 1, 2-azidophenyl isocyanide 2, or 2-nitrophenyl isocyanide 3 with complexes [Mo(CO)3(dppe)(py)] [4] or [W(CO)3(dppe)(N≡CCH3)] [5] yields the isocyanide complexes [Mo(CO)3(dppe)(C≡NR)] ([6]: C≡NR = 1; [12]: C
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::178e019fcc61577987041c94da1726d6
https://doi.org/10.1021/om301067v
https://doi.org/10.1021/om301067v