Zobrazeno 1 - 10
of 68
pro vyhledávání: '"Chockalingam Srinivasan"'
Publikováno v:
Research Letters in Organic Chemistry. 2009:1-4
Increasing awareness of environmental hazards forces chemists to look for “eco-friendly” reaction conditions. In this connection, the use of heterogeneous catalysts involving solid reagents supported on high surface area materials, obtained by in
Publikováno v:
Journal of the Chemical Society, Perkin Transactions 2. :2125-2129
Kinetic measurements of the oxidation of divalent organic sulfur compounds by N-chlorosuccinimide in acetonitrile–water mixture at constant [H+] show that the reaction is first order in both the oxidant and the organic sulfur compound. While the ra
Publikováno v:
Journal of Photochemistry and Photobiology A: Chemistry. 149:131-137
Photohydroxylation of 4-nitroveratrole in the presence of cyclodextrins results in regioselective formation of 2-methoxy-4-nitrophenol as the exclusive product. This is in contrast to solution photolysis, wherein isomeric 2-methoxy-5-nitrophenol is t
Publikováno v:
Tetrahedron. 58:4283-4290
The oxygenation of aryl methyl sulfides and diaryl sulfides by peroxomonophosphoric acid in acetonitrile–water mixture follows an overall second-order kinetics, first-order in each reactant. The study of the influence of [H + ] on the oxidation of
Publikováno v:
Applied Catalysis A: General. 223:129-135
In the TiO2-photocatalyzed oxidation of benzhydrol in oxygen-purged acetonitrile, benzophenone was observed to be the sole product. The influence of various parameters, like irradiation time, amount of catalyst, concentration of catalyst and other fa
Publikováno v:
Journal of Inclusion Phenomena and Macrocyclic Chemistry. 43:207-211
In contrast to the formation of meso-stilbene dibromide as the major productin the electrophilic addition of bromine to trans-stilbene in nonpolar solvents,stereoselectivity decreases in cyclodextrin cavities and a significant yield ofdl-stilbene dib
Induced diastereoselectivity in photodecarboxylation of 2-phenylpropionic acid in faujasite zeolites
Publikováno v:
Tetrahedron. 57:4455-4459
Irradiation of 2-phenylpropionic acid in various cation-exchanged faujasites leads to predominant formation of dl -2,3-diphenylbutane over the meso -isomer (in marked contrast to photolysis in isotropic media) and this zeolite-induced diastereoselect
Publikováno v:
Tetrahedron. 57:1369-1374
The kinetics of oxygenation of the title sulphoxides by peroxomonophosphoric acid in aqueous acetic acid follows an overall second-order kinetics, first-order in each reactant. An analysis of the influence of [H+] reveals that H3PO5 is the active spe
Autor:
Chockalingam Srinivasan, Kuang-Lieh Lu, George Allen Gnanaraj, Balasubramanian Manimaran, B. Venkatachalapathy, Pounraj Thanasekaran, Perumal Ramamurthy, Seenivasan Rajagopal, Thangamuthu Rajendran
Publikováno v:
Physical Chemistry Chemical Physics. 3:2063-2069
The rate constants (kq) for the photoinduced electron transfer reactions of Ru(II)-polypyridyl complexes (Ru(NN)32+) with 2,6-disubstituted phenolate ions in aqueous acetonitrile are highly sensitive to change in the bulkiness of the ligand in Ru(NN)
Publikováno v:
Journal of Molecular Catalysis A: Chemical. 160:429-435
Acidic zeolites HY and CaY catalyse the Wallach rearrangement of azoxybenzene ( I ) leading mainly to the formation of para -hydroxyazobenzene ( II ) and ortho -hydroxyazobenzene ( III ). In this transformation, increasing the loading level of I resu