Zobrazeno 1 - 10
of 20
pro vyhledávání: '"Chitti Srinivas"'
Publikováno v:
Tetrahedron: Asymmetry. 22:2124-2133
The synthesis of gingerol 1 and related compounds 2 – 5 along with diarylheptanoids 6 – 8 has been accomplished using a Keck allylation, Crimmins’ aldol reaction, aldehyde coupling with acetylene, and chelation controlled reductions as the key
Publikováno v:
Tetrahedron: Asymmetry. 22:2071-2079
The synthesis of (4 R ,6 S ,7 R )-7-hydroxy-4,6-dimethyl-3-nonanone and (3 R ,5 S ,6 R )-6-hydroxy-3,5-dimethyl-2-octanone is described as their acetates using a desymmetrization strategy as well as an Evans syn aldol strategy.
Publikováno v:
Helvetica Chimica Acta. 94:224-229
The total synthesis of aspinolide A (1) was successfully achieved by an iterative acetyleneepoxide coupling strategy and a Yamaguchi lactonization as the key steps.
Publikováno v:
Helvetica Chimica Acta. 93:1634-1640
The total synthesis of herbarumin III (1) was achieved via an alkynide ion addition onto a chiral aldehyde and LiAlH4/LiI reduction as key steps (Scheme 2).
Autor:
M. Rajkumar, Chitti Srinivas, Chittapragada Maruthi, Gowravaram Sabitha, Jhillu S. Yadav, Kadari Sudhakar
Publikováno v:
Synthesis. 2007:3886-3890
An enantioselective route for the synthesis of (6 S)-5,6-dihydro-6-[(2 R)-2-hydroxy-6-phenylhexyl]-2 H-pyran-2-one is reported. The synthesis is based on epoxide ring opening with a Grignard reagent and stereoselective reduction employing catecholbor
Autor:
Chitti Srinivas, Jhillu S. Yadav, Ajit C. Kunwar, Erigala Venkata Reddy, Gowravaram Sabitha, Samit Kumar Dutta, Chittapragada Maruthi
Publikováno v:
Helvetica Chimica Acta. 89:2728-2731
A novel, efficient synthesis of a series of functionalized, benzo-annelated decahydrofuro[3,2-h][1,6]naphthyridine derivatives 3 has been achieved. The protocol is based on the intramolecular hetero-Diels–Alder (IMHDA) reaction of in situ formed im
Publikováno v:
Bulletin of the Chemical Society of Japan. 84:229-231
The synthesis of an eight-membered lactone, cephalosporolide D is described using an iterative acetylene–epoxide coupling strategy. The terminal triple bond compound prepared in situ from the known...
Publikováno v:
ChemInform. 42
Title compound (VI) is synthesized using an iterative acetylene-epoxide coupling [ (III)] and a Yamaguchi lactonization as the key steps.
Publikováno v:
Synlett. 2001:0854-0856
Several aromatic and aliphatic sulphoxides are selectively deoxygenated to the corresponding thioethers in high to quantitative yields by samarium metal in methanolic ammonium chloride under sonication. Other functional groups such as halides, esters
Publikováno v:
ChemInform. 41
Advantages of this method are its generality, short reaction time, easy workup, and ease of recovery and reuse of the catalyst.