Zobrazeno 1 - 10
of 15
pro vyhledávání: '"Chikashi Kanazawa"'
Autor:
Masahiro Terada, Chikashi Kanazawa
Publikováno v:
Chemistry - An Asian Journal. 4:1668-1672
Publikováno v:
Synlett. 2009:638-642
The tandem addition-cyclization reaction between o-alkynylbenzaldehyde and nucleophile catalyzed by P4- t Bu, a phosphazene base, is demonstrated. The nucleophilic cyclization is efficiently triggered not only by alcohols, including sterically demand
Publikováno v:
Angewandte Chemie. 117:7896-7899
Autor:
Masahiro Terada, Chikashi Kanazawa
Publikováno v:
Tetrahedron Letters. 48:933-935
The organic-base-catalyzed 5-exo intramolecular cyclization reaction of o-alkynylbenzoic acid produces the corresponding phthalide regioselectively in good to excellent yields. The method provides a practical access to the phthalides, an important cl
Autor:
Masahiro Terada, Chikashi Kanazawa
Publikováno v:
ChemInform. 41
Publikováno v:
ChemInform. 41
Publikováno v:
ChemInform. 40
Publikováno v:
ChemInform. 39
Theoretical studies of the organic base-catalyzed 5-exo intramolecular cyclization of o-alkynylbenzoic acid were documented. The acidic fragment participating in the transition states was shown to reduce the activation energy significantly on the bas
Publikováno v:
Journal of the American Chemical Society. 127(25)
The copper-catalyzed reaction of isocyanides (CNCH2EWG1) 1 with electron-deficient alkynes (RC[triple bond]CEWG2) 2 gave the 2,4-di-EWG-substituted pyrroles 3 selectively, whereas the phosphine-catalyzed reaction of 1 with 2 afforded the 2,3-di-EWG-s
Publikováno v:
Journal of the American Chemical Society. 128:10662-10663
The copper-catalyzed reaction between two different isocyanides produces the corresponding heteroaromatization products, imidazoles, in good yields. The reaction proceeds most probably through the activation of the sp3 C−H bond in the isocyanides b