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Autor:
Allison Mills, Susannah L. Scott, Jean-Marie Basset, Nicolas Millot, Chhor Chao, Catherine Santini
Publikováno v:
Journal of Molecular Catalysis A: Chemical. :457-463
The reaction of the silica-supported complex (SiO)(SiOX)Rh(η3-C3H5)2, where X is H or Si, with excess PiPr3 leads to the formation of the chemisorbed bis(phosphine) Rh(I) complex [SiORh(PiPr3)2]x, proposed to be dimeric (x=2) on the basis o