Zobrazeno 1 - 3
of 3
pro vyhledávání: '"Cheryl J. A. McCaw"'
Publikováno v:
European Journal of Organic Chemistry. 2008:4200-4205
The kinetics of the reaction of 4-nitrophenyl sulfamate NH2SO2OC6H4NO2-4 (1a) in acetonitrile (ACN) with a series of pyridines (pKa range ca. 8 units) and alicyclic amines (pKa range ca. 3.6 units) has been studied in the presence of excess amine at
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::4cd72ac0f53b99c733ae27d8738b24ae
https://doi.org/10.1002/ejoc.200800366
https://doi.org/10.1002/ejoc.200800366
Publikováno v:
Journal of Physical Organic Chemistry. 19:512-517
Many compounds containing a sulfamate moiety, such as NH2SO2O are now known to be medicinally important. However, very little is known about their mechanisms of reaction even under non-biological conditions. In this work the various types of eliminat
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::7953bd4a33fdfcce8f24176f4cea614d
https://doi.org/10.1002/poc.1050
https://doi.org/10.1002/poc.1050
Autor:
Giorgio Cevasco, William J. Spillane, Neil P. Maguire, Sergio Thea, Cheryl J. A. McCaw, Michael J. Hynes
Publikováno v:
Organicbiomolecular chemistry. 9(2)
The kinetics of hydrolysis at medium acid strength (pH interval 2-5) of a series of phenylsulfamate esters 1 have been studied and they have been found to react by an associative S(N)2(S) mechanism with water acting as a nucleophile attacking at sulf
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9db9080302d64cf0b01fe496633a8c20
https://pubmed.ncbi.nlm.nih.gov/20976313
https://pubmed.ncbi.nlm.nih.gov/20976313