Ammonium zincates as suitable catalyst for the room temperature cycloaddition of CO2 to epoxides

Autor: Nicola Panza, Matteo Alberti, Caterina Damiano, Alessandro Caselli

Publikováno v: Frontiers in Catalysis, Vol 2 (2022)

We have recently shown that simple ammonium ferrates are competent catalyst for the cycloaddition reaction of CO2 to epoxides under moderate reaction conditions (T = 100°C, P(CO2) = 0.8 MPa). We report here that ammonium zincates of general formulae

Externí odkaz: https://doaj.org/article/c17173601df04568be36ed514394f1b4

Ammonium zincates as suitable catalyst for the room temperature cycloaddition of CO2 to epoxides

Autor: Panza, N., Alberti, M., Damiano, C., Caselli, A.

Publikováno v: Frontiers in Catalysis. 2

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=dedup_wf_001::c3f11f9ff8e6528b5ad45687d2e6020e

Experimental and theoretical insight into the mechanism of CO2 cycloaddition to epoxides catalyzed by ammonium ferrates

Autor: Nicola Panza (a), Raffaella Soave (b), Fausto Cargnoni (b), Mario Italo Trioni (b), Alessandro Caselli (a

Publikováno v: Journal of CO2 Utilization 62 (2022): 1–10. doi:10.1016/j.jcou.2022.102062
info:cnr-pdr/source/autori:Nicola Panza (a), Raffaella Soave (b), Fausto Cargnoni (b), Mario Italo Trioni (b), Alessandro Caselli (a, b)/titolo:Experimental and theoretical insight into the mechanism of CO2 cycloaddition to epoxides catalyzed by ammonium ferrates/doi:10.1016%2Fj.jcou.2022.102062/rivista:Journal of CO2 Utilization/anno:2022/pagina_da:1/pagina_a:10/intervallo_pagine:1–10/volume:62

Soluble tetrabutylammonium ferrates, [TBA][FeX3Y] (TBA = nBu4N) were synthetized by treating ferric salts (FeX3) with tetrabuthylammoniom halides. Their activity as a stand-alone catalyst in CO2 cycloaddition reactions to epoxides was assessed under

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=doi_dedup___::a6a16ed7442342af7e511e75d6707ac5
https://hdl.handle.net/2434/929093

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