Zobrazeno 1 - 10
of 53
pro vyhledávání: '"Chelladurai Ganesamoorthy"'
Autor:
Chelladurai Ganesamoorthy, Christoph Helling, Christoph Wölper, Walter Frank, Eckhard Bill, George E. Cutsail, Stephan Schulz
Publikováno v:
Nature Communications, Vol 9, Iss 1, Pp 1-8 (2018)
Radicals of heavy main-group elements represent important intermediates in chemical synthesis, yet few have been isolated. Here the authors stabilize neutral stibinyl and bismuthinyl radicals using gallium-based ligands, and reduce the former to affo
Externí odkaz:
https://doaj.org/article/d5140502220e4a1cb90d07b971497c8f
Autor:
Juliane Schoening, Chelladurai Ganesamoorthy, Christoph Wölper, Ephrath Solel, Peter R. Schreiner, Stephan Schulz
Publikováno v:
Dalton Transactions. 51:8249-8257
Room-temperature stable main group element carbonyl complexes are rare. Here we report on the synthesis of two such complexes, namely gallium-substituted silylene-carbonyl complexes [L(X)Ga]2SiCO (X = I 2, Me 3; L = HC[C(Me)NDipp]2, Dipp = 2,6-iPr2C6
Publikováno v:
Dalton Transactions. 51:2050-2058
The activation of relatively inert E-X σ-bonds by low-valent main group metal complexes is receiving increasing interest. We here confirm the promising potential of gallanediyl LGa (L = HC[C(Me)N(Dip)]2, Dip = 2,6-i-Pr2C6H3) to activate E-Cl (E = C,
Autor:
Peter R. Schreiner, Lijuan Song, Christoph Wölper, Juliane Schoening, Stephan Schulz, Chelladurai Ganesamoorthy
Publikováno v:
Nature Chemistry. 12:608-614
Main-group-element compounds with energetically high-lying donor and low-lying acceptor orbitals are able to mimic chemical bonding motifs and reactivity patterns known in transition metal chemistry, including small-molecule activation and catalytic
The oxidation reactions of ArSb [Ar = 2,6-(HC=N-t-Bu)2C6H3] with S8, grey Se and Te as well as E2Ph2 (E = S, Se, Te) are demonstrated. The reactions of ArSb with elemental sulfur and selenium occurred at elevated temperatures and yielded ArSbE (E = S
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2a733e3050271707a5b40251f9e6ca41
https://duepublico2.uni-due.de/receive/duepublico_mods_00073538
https://duepublico2.uni-due.de/receive/duepublico_mods_00073538
Autor:
Anton S. Nizovtsev, Chelladurai Ganesamoorthy, Julia Krüger, Stephan Schulz, Christoph Wölper
[Cp*Sb]4 (Cp*=C5 Me5 ) reacts with [L1 Mg]2 and L2 Ga with formation of [(L1 Mg)4 (μ4 ,η1:2:2:2 -Sb4 )] (L1 =iPr2 NC[N(2,6-iPr2 C6 H3 )]2 , 1) and [(L2 Ga)2 (μ,η2:2 -Sb4 )] (L2 =HC[C(Me)N(2,6-iPr2 C6 H3 )]2 , 2). The cleavage of the Sb-Sb and Sb-
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::034e006fc22db15ad8b2c6016c4d26c8
Equimolar amounts of LGa (L = [(2,6-i-Pr2-C6H3)NC(Me)]2CH) and InEt3 were found to react with insertion into the In–carbon bond and formation of LGa(Et)InEt2 (1), while in the presence of the N-heterocyclic carbene It-Bu [C(Nt-Bu2CH)2], the base-st
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::469b7ace6e462ce84c14961cc517c3d1
https://duepublico2.uni-due.de/receive/duepublico_mods_00073457
https://duepublico2.uni-due.de/receive/duepublico_mods_00073457
RGa {R=HC[C(Me)N(2,6‐iPr2C6H3)]2} reagiert mit Sb(NMe2)3 unter Insertion in die Sb‐N‐Bindung und der Eliminierung von RGa(NMe2)2 (2), gefolgt von der Bildung eines Ga‐substituierten Distibens R(Me2N)GaSb=SbGa(NMe2)R (1). Die Thermolyse von 1
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::5d68314f1dae28e39fb464bc7e496706
https://duepublico2.uni-due.de/servlets/MCRFileNodeServlet/duepublico_derivate_00073244/Accepted_Manuscript_Angew_Chem_2015_127_10803.pdf
https://duepublico2.uni-due.de/servlets/MCRFileNodeServlet/duepublico_derivate_00073244/Accepted_Manuscript_Angew_Chem_2015_127_10803.pdf
Six alkali metal complexes of partly‐fluorinated, donor‐functionalized β‐ketoiminate ligands [L1Li (1), L1Na (2), L1K (3), L1Cs (4), L1 = OC(CF3)CHC(CH3)NCH2CH2OCH3; L2Li (5), L2Na (6), L2 = OC(CF3)CHC(CH3)NCH2CH2N(CH3)2] were prepared and str
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::cd27d31479074d5379aadcac867924db
https://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&origin=inward&scp=85077072255
https://www.scopus.com/inward/record.url?partnerID=HzOxMe3b&origin=inward&scp=85077072255
Autor:
Rémi Marchal, Chelladurai Ganesamoorthy, Jana Weßing, Samia Kahlal, Roland A. Fischer, Jean-Yves Saillard, Juarez L. F. Da Silva, Christian Gemel, Olivier Cador, Augusto C. H. Da Silva
Publikováno v:
Angewandte Chemie. 130:14840-14844