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pro vyhledávání: '"Cheletropic reaction"'
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Publikováno v:
Phosphorus, Sulfur, and Silicon and the Related Elements. 196:414-421
The [4 + 2] cycloaddition reaction (McCormack reaction) of 1,3-butadiene with dichloromethylphosphine (DCMP) yielding 3-phospholene oxide has been studied by density functional theory (DFT) at the M06-2x/6-311++G(2d,2p) computational level. This reac
Publikováno v:
Advanced Journal of Chemistry-Section A. :117-126
In this research DFT calculations were used to investigate the neighboring effects on cheletropic reaction of 2,5-Dihydrothiophene sulfone(1). Structural properties and stereoelectronic behavior in the activation energy and enthalpy of cheletropic re
Publikováno v:
Canadian Journal of Chemistry. 96:139-143
UiO-66 and a muconic acid functionalized derivative of UiO-66 (UiO-66-MA) were synthesized via the solvothermal method to determine if the muconic acid could undergo a cheletropic reaction in the presence of sulfur dioxide inside the metal-organic fr
Publikováno v:
Sensors and Actuators B: Chemical. 346:130562
The biorelevance of nitric oxide (NO) has attracted intensive efforts in their in situ detection. Fluorescence-based methods have been established as the benchmark due to their sensitivity. The high stability and radical nature of NO contributed to t
Publikováno v:
Chemistry (Weinheim an Der Bergstrasse, Germany)
We describe here a di‐(β,β′‐sulfoleno)pyrrin programmed for efficient and specific β,β′‐functionalization via [4+2] cycloaddition reactions. At 120 °C and in the presence of an excess of C60‐fullerene the di‐(β,β′‐sulfoleno)p
Publikováno v:
Bioorganic & Medicinal Chemistry. 44:116297
Delivering a therapeutically active gaseous molecule represents very unique challenges in terms of both precise dosing and concentration assessment. To overcome these obstacles, there have been recent reports of using prodrug approaches for the in-vi
Autor:
Zinatossadat Hossaini, Samaneh Vaseghi, Seyyedeh Fatemeh Mousavi, Rezvaneh Rostamian, Elham Ezzatzadeh
Publikováno v:
Journal of Heterocyclic Chemistry. 54:2906-2911
A series of oxocyclopenta[c]chromenes were synthesized via three component reaction of 4-hydroxycumarin, dialkyl acetylenedicarboxylate, α-bromo ketones, and triphenylphosphine in the presence of catalytic amount of Fe3O4 magnetic nanoparticles (MNP
Publikováno v:
Organic Chemistry Frontiers. 3:480-485
The mechanism of the ring contraction reaction of (η4-1,2-disilacyclohexadiene)iron tricarbonyls was studied at the M06/LACVP* level. The Si–Si bond of (η4-1,2-disilacyclohexadiene)iron tricarbonyls 1 was initially broken to form an η4-intermedi
Autor:
Mehdi Bakavoli, Fariborz Ziaee, Hossein Sabet-Sarvestani, Nazanin Noroozi-Shad, Hossein Eshghi, Mohammad Izadyar
Publikováno v:
Journal of Chemical Research. 39:635-639
Kinetic and thermodynamic aspects of the retro cheletropic reaction of sulfur dioxide extrusion have been investigated. The interaction of the X–S bond (X=NH, S, O and CH2) and oxygen lone pairs of SO2 showed remarkable stereoelectronic effects and