Synthesis, characterization and photochemical properties of 3d transition metal supported by aroyl-hydrazone ligands

Autor: Cheaib, Khaled

Ce travail de thèse explorait certains aspects de la chimie de coordination de complexes moléculaires à bases de métaux 3d (Fe, Cu, Mn et Ni) supportés par des ligands azotés de type aroyle-hydrazone. Le travail de cette thèse était plus part

Externí odkaz: http://www.theses.fr/2013STRAF062/document

Synthesis, crystal structures and use in ethylene oligomerization catalysis of novel mono- and dinuclear nickel complexes supported by (E)-N′-(1-(thiophen-2-yl)ethylidene)benzohydrazide ligand

Autor: Zuo, Weiwei, Tourbillon, Clarisse, Rosa, Vitor, Cheaib, Khaled, Andrade, Marta M., Dagorne, Samuel, Welter, Richard

Publikováno v: In Inorganica Chimica Acta 30 March 2012 383:213-219

Selective Formation of an Fe^IVO or an Fe^IIIOOH Intermediate From Iron(II) and H2O2: Controlled Heterolytic versus Homolytic Oxygen–Oxygen Bond Cleavage by the Second Coordination Sphere.

Autor: Cheaib, Khaled¹, Mubarak, M. Qadri E.², Sénéchal‐David, Katell¹, Herrero, Christian¹, Guillot, Régis¹, Clémancey, Martin³, Latour, Jean‐Marc³, de Visser, Sam P.² sam.devisser@manchester.ac.uk, Mahy, Jean‐Pierre¹, Banse, Frédéric¹ frederic.banse@u-psud.fr, Avenier, Frédéric¹ frederic.avenier@u-psud.fr

Publikováno v: Angewandte Chemie. Jan2019, Vol. 131 Issue 3, p864-868. 5p.

Circumventing Intrinsic Metal Reactivity: Radical Generation with Redox-Active Ligands.

Autor: Jacquet, Jérémy¹, Cheaib, Khaled¹, Ren, Yufeng¹, Vezin, Hervé², Orio, Maylis³, Blanchard, Sébastien¹, Fensterbank, Louis¹, Desage‐El Murr, Marine^1,4 marine.desage-el_murr@upmc.fr

Publikováno v: Chemistry - A European Journal. 10/26/2017, Vol. 23 Issue 60, p15030-15034. 5p.

Selective Formation of an FeIVO or an FeIIIOOH Intermediate From FeII-H2O2 : Controlled Heterolytic vs Homolytic O-O Bond Cleavage by the Second Coordination Sphere

Autor: Cheaib, Khaled, Mubarak, Muhammad Qadri Effendy, Sénéchal-david, Katell, Herrero, Christian, Guillot, Régis, Clémancey, Martin, Latour, Jean-marc, De Visser, Samuel, Mahy, Jean-pierre, Banse, Frédéric, Avenier, Frederic

Publikováno v: Cheaib, K, Mubarak, M Q E, Sénéchal-david, K, Herrero, C, Guillot, R, Clémancey, M, Latour, J, De Visser, S, Mahy, J, Banse, F & Avenier, F 2018, ' Selective Formation of an FeIVO or an FeIIIOOH Intermediate From FeII-H2O2 : Controlled Heterolytic vs Homolytic O-O Bond Cleavage by the Second Coordination Sphere ', Angewandte Chemie International Edition . https://doi.org/10.1002/anie.201812724

We demonstrate that the devised incorporation of an alkylamine group into the second coordination sphere of an FeII complex allows to switch its reactivity with H2O2 from the usual formation of FeIII species towards the selective generation of an FeI

Externí odkaz: https://explore.openaire.eu/search/publication?articleId=od______3818::28e29c14f5f6f364537e1dd67796a27d
http://doi.wiley.com/10.1002/anie.201812724