Zobrazeno 1 - 10
of 16
pro vyhledávání: '"Charles C. Mokhtarzadeh"'
Publikováno v:
Journal of the American Chemical Society. 140:8100-8104
Reported here is the isolation of a dianionic cobalt terminal carbyne derived from chemical reduction of an encumbering isocyanide ligand. Crystallographic, spectroscopic and computational data reveal that this carbyne possesses a low-valent cobalt c
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::2ec830fa145f3408d1b35f0812ae749d
https://doi.org/10.1021/jacs.8b05019
https://doi.org/10.1021/jacs.8b05019
Autor:
Mohand Melaimi, Curtis E. Moore, Myles J. Drance, Arnold L. Rheingold, Joshua S. Figueroa, Charles C. Mokhtarzadeh, Douglas W. Agnew
Publikováno v:
Angewandte Chemie International Edition. 57:13057-13061
Multimetallic clusters have long been investigated as molecular surrogates for reactive sites on metal surfaces. In the case of the μ4 -nitrido cluster [Fe4 (μ4 -N)(CO)12 ]- , this analogy is limited owing to the electron-withdrawing effect of carb
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::574e1c85a3f3242358e24ae1d34bd11d
https://doi.org/10.1002/anie.201801206
https://doi.org/10.1002/anie.201801206
Publikováno v:
Angewandte Chemie. 129:11034-11039
The encumbered tetraisocyanide dianion Na2 [Fe(CNArMes2 )4 ] reacts with two molecules of CO2 to effect reductive disproportionation to CO and carbonate ([CO3 ]2- ). When the reaction is performed in the presence of silyl triflates, reductive disprop
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::83f0eed3d994f32a923cbffa1443785a
https://doi.org/10.1002/ange.201705877
https://doi.org/10.1002/ange.201705877
Autor:
Joshua S. Figueroa, Daniel P. Spence, Charles C. Mokhtarzadeh, Alex E. Carpenter, Arnold L. Rheingold, Douglas W. Agnew, Nils Weidemann, Curtis E. Moore, Mohand Melaimi
Publikováno v:
Organometallics. 36:2126-2140
The dimeric bridging carbonyl complexes [(μ-CO)2[CpCo]2]n (n = 0, 1−) have occupied a central position in the understanding of metal–metal bonding interactions when bridging ligands are present. Based on simple electron-counting formalisms, thes
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::6fc74fc978d1a8f35a82427aa627fb1f
https://doi.org/10.1021/acs.organomet.7b00164
https://doi.org/10.1021/acs.organomet.7b00164
Autor:
Curtis E. Moore, Joshua S. Figueroa, Charles C. Mokhtarzadeh, Arnold L. Rheingold, Chinglin Chan
Publikováno v:
Journal of the American Chemical Society. 141(38)
Despite its utility as an oxygen-atom transfer reagent for transition metals, nitrous oxide (N2O) is a notoriously poor ligand, and its coordination chemistry has been limited to a few terminal, end-on κ1-N complexes. Here, the synthesis of a mononu
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ca52720e77057a9417837c7760f17662
https://pubmed.ncbi.nlm.nih.gov/31492053
https://pubmed.ncbi.nlm.nih.gov/31492053
Autor:
Brooke N. Livesay, James M. Boncella, Charles C. Mokhtarzadeh, John McCracken, Brennan S. Billow, Matthew P. Shores, Aaron L. Odom
Publikováno v:
Journal of the American Chemical Society. 140(50)
Reduction of IU(NHAriPr6)2 (AriPr6 = 2,6-(2,4,6-iPr3C6H2)2C6H3) results in a rare example of a U(II) complex, U(NHAriPr6)2, and the first example that is a neutral species. Here, we show spectroscopic and magnetic studies that suggest a 5f46d0 valenc
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::9b2271cc1d8d563b73e4d868867d4448
https://pubmed.ncbi.nlm.nih.gov/30500184
https://pubmed.ncbi.nlm.nih.gov/30500184
Autor:
Joshua S. Figueroa, Curtis E. Moore, Andrew J. McNeece, Charles C. Mokhtarzadeh, Arnold L. Rheingold
Publikováno v:
Journal of Coordination Chemistry. 69:2059-2068
The pentachloroethyl complex NiCl(CCl2CCl3)(CNArMes2)2 (ArMes2 = 2,6-(2,4,6-Me3C6H2)2C6H3) was recently shown to be a unique example of an isolable β-chloroalkyl complex of square planar nickel. In an effort to generate additional β-haloalkyl compl
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::947ae3d1bc05c0d7ce8e4820937cdfb6
https://doi.org/10.1080/00958972.2016.1172702
https://doi.org/10.1080/00958972.2016.1172702
Publikováno v:
Dalton Transactions. 45:14561-14569
Synthetic studies targeting an m-terphenyl isocyanide analogue of the unstable 16e(-), S = 1 complex CpCo(CO) are reported (Cp = η(5)-C5H5). The m-terphenyl isocyanide CNAr(Dipp2) (Ar(Dipp2) = 2,6-(2,6-(i-Pr)2C6H3)2C6H3) is shown to readily bind to
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::ce35f23252139d92e51c24c037e9f235
https://doi.org/10.1039/c6dt02789j
https://doi.org/10.1039/c6dt02789j
Autor:
Brandon R. Barnett, Charles C. Mokhtarzadeh, Joshua S. Figueroa, Paul Lummis, Shuai Wang, Joshua D. Queen, John Gavenonis, Nicolas Schüwer, T. Don Tilley, Jessica N. Boynton, Philip P. Power, Treffly B. Ditri, Nils Weidemann, Douglas W. Agnew, Patrick William Smith, Alex E. Carpenter, Jade K. Pratt, Noah D. Mendelson
Publikováno v:
Inorganic Syntheses
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_________::c2c5a5a097cfa7d0c997f302ff0ae5aa
https://doi.org/10.1002/9781119477822.ch5
https://doi.org/10.1002/9781119477822.ch5
Publikováno v:
Inorganic Chemistry. 50:5105-5112
Reaction of the uranyl β-ketoiminate complex UO(2)((tBu)acnac)(2) (1) ((tBu)acnac = (t)BuNC(Ph)CHC(Ph)O) with Me(3)SiI, in the presence of Ph(3)P, results in the reductive silylation of the uranyl moiety and formation of the U(V) bis-silyloxide comp
Externí odkaz:
https://explore.openaire.eu/search/publication?articleId=doi_dedup___::6ff61a4cc34c7ebf51fff7c1f04a775f
https://doi.org/10.1021/ic200387n
https://doi.org/10.1021/ic200387n